Електропровідність поверхні плівок SnO2:Sb, модифікованої Pd і Pt

Using the molten precursor (KNO3, 400 °C), SnO2:Sb nanoparticles with surface modified with Pd and Pt atoms have been synthesized. Their morphology, phase composition, concentration of dopants have been studied. The influence of adsorption of air oxygen, ethanol, and acetone vapour (0.5–350 ppm) on...

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Datum:2014
Hauptverfasser: Panov, E. V., Milovanova, O. I., Malyovanyi, S. M., Genkina, E. A.
Format: Artikel
Sprache:Russisch
Veröffentlicht: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2014
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Online Zugang:https://www.cpts.com.ua/index.php/cpts/article/view/291
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Назва журналу:Chemistry, Physics and Technology of Surface

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Chemistry, Physics and Technology of Surface
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Zusammenfassung:Using the molten precursor (KNO3, 400 °C), SnO2:Sb nanoparticles with surface modified with Pd and Pt atoms have been synthesized. Their morphology, phase composition, concentration of dopants have been studied. The influence of adsorption of air oxygen, ethanol, and acetone vapour (0.5–350 ppm) on the electroconductivity G of SnO2:Sb, М/SnO2:Sb (М = Pd, Pt, Pd + Pt) films at the temperature of 20–250 °С has been examined. It has been found that simultaneous doping with Pd and Pt increases the concentration of oxygen in the О– form on the film, improves the kinetics of gas-analyte oxidation, shifts the gas sensitivity to the region of low temperatures (200 °С). At this way the time stability of the film is retained.