Ємність подвійного електричного шару та динамічні нестійкості
Based on impedance spectroscopy theory, the influence has been studied of electrical double layer capacitance on appearance of periodic oscillations and bistability in a model electrochemical system with potential-dependent adsorption/desorption of electroactive species and a preceding chemical reac...
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| Date: | 2015 |
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| Main Author: | |
| Format: | Article |
| Language: | Ukrainian |
| Published: |
Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine
2015
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| Subjects: | |
| Online Access: | https://www.cpts.com.ua/index.php/cpts/article/view/348 |
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| Journal Title: | Chemistry, Physics and Technology of Surface |
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Chemistry, Physics and Technology of Surface| Summary: | Based on impedance spectroscopy theory, the influence has been studied of electrical double layer capacitance on appearance of periodic oscillations and bistability in a model electrochemical system with potential-dependent adsorption/desorption of electroactive species and a preceding chemical reaction in the Nernst diffusive layer atplanar electrode. It has been shown that the influence of the parameter in question is essential only in high-frequency range, that is why taking it into account does not change the position of the bifurcation points of the system. |
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