Ємність подвійного електричного шару та динамічні нестійкості
Based on impedance spectroscopy theory, the influence has been studied of electrical double layer capacitance on appearance of periodic oscillations and bistability in a model electrochemical system with potential-dependent adsorption/desorption of electroactive species and a preceding chemical reac...
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| Datum: | 2015 |
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| 1. Verfasser: | |
| Format: | Artikel |
| Sprache: | Ukrainisch |
| Veröffentlicht: |
Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine
2015
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| Schlagworte: | |
| Online Zugang: | https://www.cpts.com.ua/index.php/cpts/article/view/348 |
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| Назва журналу: | Chemistry, Physics and Technology of Surface |
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Chemistry, Physics and Technology of Surface| Zusammenfassung: | Based on impedance spectroscopy theory, the influence has been studied of electrical double layer capacitance on appearance of periodic oscillations and bistability in a model electrochemical system with potential-dependent adsorption/desorption of electroactive species and a preceding chemical reaction in the Nernst diffusive layer atplanar electrode. It has been shown that the influence of the parameter in question is essential only in high-frequency range, that is why taking it into account does not change the position of the bifurcation points of the system. |
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