Використання радіаційно-індукованої полімеризації для отримання сорбційно-активних поліпропіленових тканин з сульфокислотними групами

Sorption active material carrying sulfonic acid groups was synthesized by radiation-induced graft polymerization of styrene monomer onto the surface of non-woven polypropylene fabric followed by sulfonation of grafted polystyrene chains. The effect of the main experimental parameters on styrene graf...

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Datum:2010
Hauptverfasser: Bondar, I. V., Han, D. H., Cho, H. K.
Format: Artikel
Sprache:Englisch
Veröffentlicht: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2010
Online Zugang:https://www.cpts.com.ua/index.php/cpts/article/view/39
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Назва журналу:Chemistry, Physics and Technology of Surface

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Chemistry, Physics and Technology of Surface
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Zusammenfassung:Sorption active material carrying sulfonic acid groups was synthesized by radiation-induced graft polymerization of styrene monomer onto the surface of non-woven polypropylene fabric followed by sulfonation of grafted polystyrene chains. The effect of the main experimental parameters on styrene grafting degree (absorbed dose, monomer concentration, reaction time) was investigated. It was found that sulfonation degree of the grafted polystyrene chains with 5% chlorosulfonic acid at room temperature depends on the reaction time and reaches 80% for the samples with a medium value of styrene grafting degree. Sorption active polypropylene fabrics with sulfonic acid group densities of 3.5–5 meq/g were obtained.