Адсорбційна система «полігідридсилоксан – благородний метал» як тригер
It is shown that «polyhydridesiloxane – solution of noble metal» systems with reducing sorption, where various Red/Ox and hydrolytic processes occur, function as original «adsorption – chemical» triggers. External factors (lyophilization of polyhydridesiloxane surface, catalytic action of nucleophil...
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| Дата: | 2010 |
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| Автори: | , , , |
| Формат: | Стаття |
| Мова: | Російська |
| Опубліковано: |
Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine
2010
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| Онлайн доступ: | https://surfacezbir.com.ua/index.php/surface/article/view/406 |
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| Назва журналу: | Surface |
| Завантажити файл: |  |
Репозитарії
Surface| Резюме: | It is shown that «polyhydridesiloxane – solution of noble metal» systems with reducing sorption, where various Red/Ox and hydrolytic processes occur, function as original «adsorption – chemical» triggers. External factors (lyophilization of polyhydridesiloxane surface, catalytic action of nucleophilic agents, contact of system with atmosphere) are the regulators of stable states – reduction of noble metal ions on developed sorbent surface and dissolution of precipitated metal phase and/or silicic base. The performed analysis for behavior of these systems is a base for elaboration of algorithms of control of the processes occurring in them. |
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