Адсорбційна система «полігідридсилоксан – благородний метал» як тригер
It is shown that «polyhydridesiloxane – solution of noble metal» systems with reducing sorption, where various Red/Ox and hydrolytic processes occur, function as original «adsorption – chemical» triggers. External factors (lyophilization of polyhydridesiloxane surface, catalytic action of nucleophil...
Saved in:
| Date: | 2010 |
|---|---|
| Main Authors: | , , , |
| Format: | Article |
| Language: | Russian |
| Published: |
Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine
2010
|
| Online Access: | https://surfacezbir.com.ua/index.php/surface/article/view/406 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Journal Title: | Surface |
| Download file: |  |
Institution
Surface| Summary: | It is shown that «polyhydridesiloxane – solution of noble metal» systems with reducing sorption, where various Red/Ox and hydrolytic processes occur, function as original «adsorption – chemical» triggers. External factors (lyophilization of polyhydridesiloxane surface, catalytic action of nucleophilic agents, contact of system with atmosphere) are the regulators of stable states – reduction of noble metal ions on developed sorbent surface and dissolution of precipitated metal phase and/or silicic base. The performed analysis for behavior of these systems is a base for elaboration of algorithms of control of the processes occurring in them. |
|---|