Гідроксид титану як сорбент для визначення мікрокількостей паладію(ІІ)

A method of synthesis of titanium hydroxide hydrogel in the capacity of transmitter for sorption catalytic test determination and semiquantitative determination of palladium (II) microquantity in solution was proposed. An optimal condition for realization the catalytic effect of microquantity of pal...

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Datum:2011
Hauptverfasser: Psareva, T. S., Tikhonova, L. P., Kobuley, O. P., Shaposhnikova, T. A.
Format: Artikel
Sprache:Russisch
Veröffentlicht: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2011
Online Zugang:https://surfacezbir.com.ua/index.php/surface/article/view/444
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Назва журналу:Surface
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Zusammenfassung:A method of synthesis of titanium hydroxide hydrogel in the capacity of transmitter for sorption catalytic test determination and semiquantitative determination of palladium (II) microquantity in solution was proposed. An optimal condition for realization the catalytic effect of microquantity of palladium (II) in reaction of oxidation of chloride-ion by manganese (III) on the surface of titanium hydrogel was found. The propositions are given about composition of manganese (III) compound in solution used for transmitter modification and on the surface of titanium hydrogel, as well about potential scheme of the mechanism of catalytic reaction on the transmitter surface.