Nonuniformity of hybrid adsorbents

Several series of pyrocarbon-mineral adsorbents (carbosils) were studied using the nitrogen adsorption method to compute structural and energetic parameters within the scope of overall adsorption isotherm approximation applying regularization procedure with consideration for surface heterogeneity. A...

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Збережено в:
Бібліографічні деталі
Дата:2001
Автори: Gun'ko, V. M., Leboda, R., Turov, V. V., Villieras, F.
Формат: Стаття
Мова:Англійська
Опубліковано: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2001
Онлайн доступ:https://surfacezbir.com.ua/index.php/surface/article/view/47
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Назва журналу:Surface
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Surface
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Резюме:Several series of pyrocarbon-mineral adsorbents (carbosils) were studied using the nitrogen adsorption method to compute structural and energetic parameters within the scope of overall adsorption isotherm approximation applying regularization procedure with consideration for surface heterogeneity. A portion of pyrocarbon deposits (graphene clusters) fills mesopores of the oxide supports, but another portion represents relatively large nonporous pyrocarbon globules formed on the outer surfaces of the oxide matrices. Contributions of these two types of pyrocarbon deposits depend on the nature of oxide matrices and carbonized precursors.