β-циклодекстринвмісний полімерний матеріал: синтез та властивості
As a result of the copolymerization reaction, an insoluble in water and organic solvents crosslinked β-cyclodextrin-containing polymer has been synthesized. The polymer is not destroyed due to prolonged contact with weakly acidic solutions, has a high sorption capacity with respect to benzoic acid a...
Збережено в:
| Дата: | 2014 |
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| Автор: | |
| Формат: | Стаття |
| Мова: | Російська |
| Опубліковано: |
Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine
2014
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| Онлайн доступ: | https://surfacezbir.com.ua/index.php/surface/article/view/539 |
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| Назва журналу: | Surface |
| Завантажити файл: |  |
Репозитарії
Surface| Резюме: | As a result of the copolymerization reaction, an insoluble in water and organic solvents crosslinked β-cyclodextrin-containing polymer has been synthesized. The polymer is not destroyed due to prolonged contact with weakly acidic solutions, has a high sorption capacity with respect to benzoic acid and good sorption kinetic parameters. Sorption results obtained are analyzed in terms of a kinetic Lagergren model for the pseudo-first and the pseudo-second order processes as well as Langmuir and Freundlich models of equilibrium adsorption. It has been shown that the interaction of benzoic acid with β-cyclodextrin-containing polymer is described by Lagergren model for pseudo-second order processes (R = 0,999). The active sites of the material synthesized are β-cyclodextrin molecules and urethane groups forming hydrogen bonds between oxygen atoms of the carboxyl group of benzoic acid molecule and hydrogen atoms of the secondary amino groups of the binder. |
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