Вплив фазового вмісту атмосферних аерозолів на кінетику їх взаємодії з леткими домішками

The influence of relative humidity of the air on the interaction kinetics of volatile impurities with components of atmospheric aerosols is described. The relations between uptake coefficients and relative humidity value are proposed to describe the experimental dependences for different systems. Th...

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Збережено в:
Бібліографічні деталі
Дата:2011
Автор: Bogillo, V. I.
Формат: Стаття
Мова:Російська
Опубліковано: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2011
Онлайн доступ:https://www.cpts.com.ua/index.php/cpts/article/view/75
Теги: Додати тег
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Назва журналу:Chemistry, Physics and Technology of Surface

Репозитарії

Chemistry, Physics and Technology of Surface
Опис
Резюме:The influence of relative humidity of the air on the interaction kinetics of volatile impurities with components of atmospheric aerosols is described. The relations between uptake coefficients and relative humidity value are proposed to describe the experimental dependences for different systems. The kinetic "resistances" model was used to describe the stationary interaction kinetics of gas with nonvolatile reactant lying in the volume of spherical particle. The limiting cases for overall rate by the individual processes are studied. The expressions are derived for ratio of surface to volume reaction rates. The ratio increases as the size of the atmospheric particle drops.