Design of functionalized polysiloxanes: synthesis and study on sulfur containing xerogels with mono- and bifunctional surface layer

Urea- and thiourea-containing trialkoxysilanes were prepared with a high yield and purity. By sol-gel processing of these precursors the new functionalized xerogels were synthesized and characterized by FTIR, elemental analysis, thermal analysis and adsorption method. Mono- and bifunctionalized xero...

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Bibliographic Details
Date:2002
Main Authors: Zub, Yu. L., Melnyk, I. V., Chuiko, A. A., Cauzzi, D., Predieri, G.
Format: Article
Language:English
Published: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2002
Online Access:https://surfacezbir.com.ua/index.php/surface/article/view/81
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Journal Title:Surface
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Summary:Urea- and thiourea-containing trialkoxysilanes were prepared with a high yield and purity. By sol-gel processing of these precursors the new functionalized xerogels were synthesized and characterized by FTIR, elemental analysis, thermal analysis and adsorption method. Mono- and bifunctionalized xerogels were easily prepared by mixing of precursors in the desired ratios together with tetraethyl orthosilicate. Obtained functional polysiloxanes are perspective materials for metal sorption and hybrid catalysis applications.