Novel polyorganosiloxane xerogels with bifunctional Si(CH2)3SH/Si(CH2)3NH2 surface layer

Novel polyorganosiloxanes gels with bifunctional ( ≡SiCH2)3SH/ ≡Si(CH2)3NH2) surface layer have been prepared by a sol-gel technique using silane-ternary systems. The surface properties of the obtained gels are highly reproducible. The effect of the addition of a catalyst was investigat...

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Збережено в:
Бібліографічні деталі
Дата:2002
Автори: Melnyk (Seredyuk), I. V., Zub, Yu. L., Chuiko, A. A., Van Der Voort, P.
Формат: Стаття
Мова:Англійська
Опубліковано: Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine 2002
Онлайн доступ:https://surfacezbir.com.ua/index.php/surface/article/view/90
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Назва журналу:Surface
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Резюме:Novel polyorganosiloxanes gels with bifunctional ( ≡SiCH2)3SH/ ≡Si(CH2)3NH2) surface layer have been prepared by a sol-gel technique using silane-ternary systems. The surface properties of the obtained gels are highly reproducible. The effect of the addition of a catalyst was investigated, and it is shown that the addition of fluoride ion has a highly beneficial effect on the porous properties of the materials. The synthesized samples have specific surface areas up to 250 m²/g, and have a high potential as selective sorbents for heavy and noble metals (Hg2+, Ag+, Au3+ etc.).