Дослідження адсорбції летючих комплексів металів з органічними лігандами
We have studied the adsorption/desorption kinetics of a number of palladium(II) volatile complexes with ?-diketones and their derivatives on polycrystalline stainless steel surface. The composition of gas phase, the order of desorption and relative activation energy, and the frequency factor have be...
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| Datum: | 2011 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | Russisch |
| Veröffentlicht: |
Chuiko Institute of Surface Chemistry National Academy of Sciences of Ukraine
2011
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| Online Zugang: | https://www.cpts.com.ua/index.php/cpts/article/view/97 |
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| Назва журналу: | Chemistry, Physics and Technology of Surface |
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Chemistry, Physics and Technology of Surface| Zusammenfassung: | We have studied the adsorption/desorption kinetics of a number of palladium(II) volatile complexes with ?-diketones and their derivatives on polycrystalline stainless steel surface. The composition of gas phase, the order of desorption and relative activation energy, and the frequency factor have been found using TPD with mass spectrometric recording of the gas phase. Physical adsorption for the entire series of compounds has been found. The most promising precursors for UV-stimulated deposition of metallic palladium films have been selected basing on the data obtained. |
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