РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРАХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ

The efficiency of combustion of liquid fuels in heat engines is determined by their hydrocarbon composition. The rate of combustion and the completeness of combustion depend on  the  hydrocarbon composition of the fuel. One of the ways to increase the efficiency of combusti...

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Date:2019
Main Authors: Leybovych, Lev, Yevstigneyev, Yurii
Format: Article
Language:English
Published: V.I.Vernadsky Institute of General and Inorganic Chemistry 2019
Online Access:https://ucj.org.ua/index.php/journal/article/view/108
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Journal Title:Ukrainian Chemistry Journal
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Ukrainian Chemistry Journal
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author Leybovych, Lev
Yevstigneyev, Yurii
author_facet Leybovych, Lev
Yevstigneyev, Yurii
author_institution_txt_mv [ { "author": "Lev Leybovych", "institution": "The Admiral Makarov National University of Shipbuilding. Nikolaev, Prospekt Geroev Ukrainy, 9, 54025" }, { "author": "Yurii Yevstigneyev", "institution": "The Admiral Makarov National University of Shipbuilding. Nikolaev, Prospekt Geroev Ukrainy, 9, 54025" } ]
author_sort Leybovych, Lev
baseUrl_str https://ucj.org.ua/index.php/journal/oai
collection OJS
datestamp_date 2026-07-22T08:23:42Z
description The efficiency of combustion of liquid fuels in heat engines is determined by their hydrocarbon composition. The rate of combustion and the completeness of combustion depend on  the  hydrocarbon composition of the fuel. One of the ways to increase the efficiency of combustion of fuel is to use fuel-hydrogen mixtures. The use of such mixtures gives prerequisites for low-temperature self-ignition of fuel droplets (about 590 °C). Preheating of the fuel gives the possibility of "explosive" combustion with increasing of the temperature up to 2500 K in 0.02 –. 0.04 ms. This leads to the intensification of heavy fuel combustion. The use of fuel-hydrogen mixtures allows to obtain a low level of harmful emissions with flue gases and to reduce emissions: CO and CH – not less than 15%, CO2 – not less than 20%. A promising direction for the creation of such mixtures is the direct dissolution of hydrogen in liquid fuel. This simplifies the flow of the fuel-hydrogen mixture into the combustion chamber of the heat engine or into the cylinders of the internal combustion engines. Analysis of previous studies showed the possibility of obtaining a single form of regression dependence for calculations of the dissolution of hydrogen in liquid fuels. The processing of the literature data and the results of our own research gave a set of regression equations for calculating the solubility of hydrogen in liquid fuels: gas, diesel, fuel oil, LVGO, HVGO, GDAR, ABVB. The obtained regression dependencies show that with increasing average molecular weight the solubility of hydrogen in the fuel decreases. These regression dependencies make it possible to obtain baseline data for the design of fuel systems for supplying fuel and hydrogen mixtures to combustion chambers of heat engines. Studies of hydrogen-diesel have shown a decrease in the flash fuel temperature by 10 – 15 oC by comparison with pure fuel. For heavy fuels, this level of reduction of the fuel round is not sufficient. Therefore, it is necessary to conduct further studies on the intensification of the process of dissolution of hydrogen in heavy fuels. This will significantly reduce energy costs for the organization of the combustion process.
doi_str_mv 10.33609/0041-6045.85.11.2019.110-116
first_indexed 2025-09-24T17:43:22Z
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fulltext Фізична хімія 110 ISSN 0041-6045. УКР . ХІМ . ЖУРН ., 2019, т . 85, No 12 UDC 541.49 : 546.284’161-32 : 547.826.1 doi 10.33609/0041-6045.85.12.2019.110-116 L.I. Leybovych ,* Y.V.Yevstigneyev REGRESSION EQUATIONS FOR CALCULATING THE SOLUBILITY OF HYDROGEN IN LIQUID FUELS The Admiral Makarov National University of Shipbuilding, Geroev Ukrainy Avenue, 9, Mykolayiv, 54025, Ukraine *e-mail: recycle.lev@gmail.com The efficiency of combustion of liquid fuels in heat engines is determined by their hydrocarbon composition. The rate of combustion and the completeness of combustion depend on the hydrocarbon composition of the fuel. One of the ways to increase the efficiency of combustion of fuel is to use fuel-hydrogen mixtures. The use of such mixtures gives prerequisites for low-temperature self- ignition of fuel droplets (about 590 °C). Preheating of the fuel gives the possibility of "explosive" combustion with increasing of the temperature up to 2500 K in 0.02 –. 0.04 ms. This leads to the intensification of heavy fuel combustion. The use of fuel-hydrogen mixtures allows to obtain a low level of harmful emissions with flue gases and to reduce emissions: CO and CH – not less than 15%, CO2 – not less than 20%. A promising direction for the creation of such mixtures is the direct dissolution of hydrogen in liquid fuel. This simplifies the flow of the fuel-hydrogen mixture into the combustion chamber of the heat engine or into the cylinders of the internal combustion engines. Analysis of previous studies showed the possibility of obtaining a single form of regression dependence for calculations of the dissolution of hydrogen in liquid fuels. The processing of the literature data and the results of our own research gave a set of regression equations for calculating the solubility of hydrogen in liquid fuels: gas, diesel, fuel oil, LVGO, HVGO, GDAR, ABVB. The obtained regression dependencies show that with increasing average molecular weight the solubility of hydrogen in the fuel decreases. These regression dependencies make it possible to obtain baseline data for the design of fuel systems for supplying fuel and hydrogen mixtures to combustion chambers of heat engines. Studies of hydrogen-diesel have shown a decrease in the flash fuel temperature by 10 – 15 oC by comparison with pure fuel. For heavy fuels, this level of reduction of the fuel round is not sufficient. Therefore, it is necessary to conduct further studies on the intensification of the process of dissolution of hydrogen in heavy fuels. This will significantly reduce energy costs for the organization of the combustion process. K e y w o r d s: hydrogen, fuel, solubility, regression dependences. INTRODUCTION. The combustion effi- ciency of liquid fuels in thermal installations is determined primarily by the hydrocarbon composition of the fuel. The combustion rate © L.I. Leybovych , Y.V.Yevstigneyev, 2019 mailto:recycle.lev@gmail.com Regression equations for calculating the solubility of hydrogen in liquid fuels ISSN 0041-6045. УКР . ХІМ . ЖУРН ., 2019, т . 85, No 12 111 and completeness of combustion depend on the hydrocarbon composition of the fuel. Therefore, the intensification of fuel com- bustion processes is an urgent task to im- prove the efficiency of heat engines. One way to solve this problem is to use hydrogen-fuel mixtures [1]. The experi- mental results show that at low concentra- tions of hydrogen in fuel – air mixtures an abnormal increase in the completeness of fuel combustion is observed. The intensifica- tion of the combustion processes of fuel - air mixtures with hydrogen additives is con- firmed by the data [2–4]. Research [1–4] was conducted on inter- nal combustion engines, in which the fuel supply system was modernized. Hydrogen was supplied to the engine cylinders simul- taneously with the supply of liquid fuel. This required the provision of a hydrogen pres- sure in the supply system exceeding the pressure of compressed air in the cylinder. This reduces the reliability of the internal combustion engine. The obtained data [1] on the intensifica- tion of the process of burning liquid fuel with small additions of hydrogen to the fuel – air mixture allow us to make an assump- tion about the possibility of using fuel- hydrogen mixtures in heat engines. In this case, we can consider the process of obtain- ing fuel-hydrogen mixtures by pre- dissolving hydrogen in fuel. This simplifies the supply of fuel-hydrogen mixture to the combustion chamber of a heat engine or to the internal combustion engine cylinders. Studies of the solubility of hydrogen in liquid fuel [5–10] allow us to conclude that the use of fuel-hydrogen mixtures in heat engines is promising. However, the process of dissolving hydrogen in liquid fuel is not well understood. The possibility of using hydrogen-fuel mixtures in heat engines re- quires additional research. The solubility of hydrogen in liquid fuel substantially depends on the hydrocarbon and fractional compositions of the fuel. The- se parameters depend on the oil field and the characteristics of the rectification process. In addition, the constant hydrocarbon and frac- tional composition of the fuel is extremely difficult to ensure during operation of the heat engine. Therefore, it is advisable to have integral characteristics for estimating the amount of hydrogen dissolved in liquid fuel when it is saturated with hydrogen. The aim of the work is to obtain regres- sion dependences for calculating the satura- tion of light fuels (diesel fuel and kerosene) with hydrogen at atmospheric pressure and a temperature of up to 60 °C. EXPERIMENT AND DISCUSSION OF THE RESULTS. Liquid fuel is a multicompo- nent mixture of organic substances Henry's law [11] for a multicomponent mixture, tak- ing into account the Wohl’s expansion [12], can be represented as: 2 1 21 3 23 13 1 3ln( ) ln( ) ln( ) aMH x H x H x x= ⋅ + ⋅ − ⋅ ⋅ (1) where H2,M – Henry's constant for a gas 2; x1 and x2 – share of solvents 1 and 3 in the mixture, respectively; H21 and H23 – Henry's constants for individual solvents, respective- ly ; a13 – the interaction parameter of the solvents from Wohl’s expansion of the ex- cess chemical potential of the ternary mix- tures. Improving the modeling of hydrogen solubility in heavy oil cuts using an Aug- mented Grayson-Streed (AGS) approach L.I. Leybovych , Y.V.Yevstigneyev 112 ISSN 0041-6045. УКР . ХІМ . ЖУРН ., 2019, т . 85, No 12 gives a significant deviation from experi- mental data [7]. This is due to the difficulty in determining the exact proportions of or- ganic matter in the fuel. Another important factor is the achievement of an equilibrium state between the gas and liquid phases. The intensity of mass transfer between phases during the ab- sorption of hydrogen by fuel is described by Fick's law [13]: ( )dcJ D dn= ⋅ , (2) where J is the diffusion flux; D is the diffu- sion coefficient of hydrogen in fuel; c is the concentration of hydrogen in fuel; n is posi- tion in the fuel layer. The rapid achievement of equilibrium between the phases can be achieved with D → ∞ or contact time τ →∞ . Parameters (D and τ) values cannot be reached equal to in- finity in real experiments .Therefore, the ex- periment time [10] was determined based on the ratio of the dissolution time of a fixed volume of hydrogen at the beginning τb of the experiment to the time of dissolution of the same volume of hydrogen at the end of the experiment τe as τe /τb = 15 – based on the recommendations [14]. The value of the dosed hydrogen volume was taken equal to 0.01 + 0.0002 L. The time of complete dissolution of hydrogen bubbles was recorded. During the experi- ment, the data obtained were entered into a program for calculating the dynamics of hy- drogen dissolution. As a result of the calcu- lation, a graph of hydrogen solubility and a regression dependence of solubility were ob- tained. An example of processing experi- mental data is shown in fig. 1: the abscissa axis is the logarithm of the time of dissolu- tion of hydrogen in the fuel (log(τ10)); the ordinate axis is the logarithm is the amount of dissolved hydrogen in the fuel (log(m1 )); the vertical line is the predicted maximum amount of hydrogen in the fuel. Fig. 1. An example of processing experi- mental data. The graph (fig.1) showed the hydrogen solubility curve and the predicted limit value of the concentration of hydrogen in the fuel. The experiment ended when the solubility of hydrogen became equal to 0.97 from the equilibrium. Based on the foregoing, it becomes ap- propriate to obtain regression equations for calculating the solubility of hydrogen in each fuel grade based on a regression analy- sis of experimental data [6–8, 10] and own experiments. Relevant physical properties for these fuels are given in table 1. The data on hydrogen solubility in fuels (table 1) are summarized in the temperature range T = 293 – 653 K and pressures P = 0 – 10 MPa by the following regression depend- ence : 2 2 ( , ) ( ) 0 1 2 ( ) 0 1 2 R P T A B A T a a T a T B P b b P b P = ⋅ = + ⋅ + ⋅ = + ⋅ + ⋅ (3) Regression equations for calculating the solubility of hydrogen in liquid fuels ISSN 0041-6045. УКР . ХІМ . ЖУРН ., 2019, т . 85, No 12 113 T a b l e 1 Characterization of fuels and experimental conditions Name of fuel, source Density, kg / l T, K P, MPa Kerosene (K) [6] 0.840 298 – 573 4.7 – 30 Fuel oil (FO) [6] 0.930 473 – 573 10.0 – 30 Light Virgin Gas Oil (LVGO) [7] 0.892 353 – 653 2.2 – 11 HeavyVirgin Gas Oil (HVGO) [7] 0.973 353 – 653 1.0 – 11 GuDao Atmospheric Residuum (GDAR) [7] 0.922 353 – 653 0.9 – 11 Athabasca Bitumen Vacuum Bottoms (ABVB) [7] 1.050 353 – 653 0.9 – 10 Diesel fuel (DF) [10] 0.847 295 – 333 Atmospheric Fuel oil [10] 0.937 295 – 333 Atmospheric T a b l e 2 The coefficients in equation (3) Fuel a0 a1 a2 b0 b1 b2 K [6] 1.69 -7.0*10-3 1.19*10-5 0.55 0.46 1.54*10-3 FO[6],[10] 0.45 -2.75*10-3 5.9*10-6 2.00 0.55 5*10-3 LVGO [7] 3.4 -0,011 8.53*10-6 0.40 1.49 0,013 HVGO [7] 3.77 -0.011 7.88*10-6 0.40 0.77 0.042 GDAR [7] 2.6 -6.22*10-3 4.81*10-6 0.083 0.954 -0.036 ABVB [7] 3.7 -0,012 7.9*10-6 0.113 0.85 -0,026 DF [10] 3.3 -0.0105 8.2*10-6 0.45 1.49 0,013 T a b l e 3 The solubility of hydrogen in various fuels at atmospheric pressure and T = 298 K Parameter K DF FO LVGO HVGO GDAR ABVB Solubility, l/l 0.363 0.405 0.309 0359 0.198 0.097 0.099 Mean molar mass, g/mol 162 144 310 250 350 1678 1700 The coefficients in equation (3) are shown in table 2. The error in determining the amount of hydrogen dissolved in the fuel ac- cording to the given regression does not ex- ceed + 8.3%. What is quite acceptable for the predictive assessment and design of fuel systems for such mixtures [15]. A graphical interpretation of experi- mental data processing in the form of paired regression (the dependence of hydrogen sol- ubility on temperature and pressure) for LVGO [7] is shown in fig. 2. L.I. Leybovych , Y.V.Yevstigneyev 114 ISSN 0041-6045. УКР . ХІМ . ЖУРН ., 2019, т . 85, No 12 Fig.2. The dependence of hydrogen solubility on temperature and pressure) for LVGO [7]. Table 3 presents data on the solubility of hydrogen in various fuels at atmospheric pressure and T = 298 K. The data in table 3 show that the solubility of hydrogen in the liquid fuel depends on the average molecular weight of the fuel. As the average molecular weight of the fuel increases, the solubility of hydrogen in it decreases. The amount of dis- solved hydrogen in light grades of fuel is quite sufficient to reduce the flash point by 10 – 15 K. Further increase of the concentra- tion of hydrogen in light fuel is not appro- priate based on the safety requirements of the heat engine. CONCLUSIONS. The obtained regression equations allow us to predict the solubility of hydrogen in liquid fuel. Light grades of fuel do not require special preparation before the process of dissolution of hydrogen at atmos- pheric pressure.For heavy fuels it is neces- sary to develop methods of intensification of the process of dissolution of hydrogen in the fuel. РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРА- ХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ Л.І.Лейбович*, Ю.В.Євстигнєєв Національний університет кораблебудування імені адмірала Макарова,. Миколаїв, просп. Героїв України, 9, Миколаїв, 54025,Україна *e-mail: recycle.lev@gmail.com Ефективність горіння рідких палив у те- плових установках визначається їх вуглевод- невим складом. Від вуглеводневого складу палива залежить швидкість його горіння і повнота згорання. Одним із шляхів підви- щення ефективності згорання палива є вико- ристання паливно-водневих сумішей, що створює передумови до виникнення низько- температурного самозаймання крапель пали- ва (близько 590 оС). Попередній розігрів па- лива дає можливість виниканню «вибухо- вого» горіння з підвищенням температури до 2500 К за 0,02 –. 0,04 мс. Це веде до інтенсифікації згорання важких палив. Засто- сування паливно-водневих сумішей дозволяє отримати низький рівень шкідливих викидів з димовими газами, і знизити викиди: СО і СН не менше 15, СО2 – не менше 20 %. Пер- спективним напрямком створення таких су- мішей є пряме розчинення водню в рідкому паливі. Це спрощує подачу паливно-водневої суміші в камеру згорання теплового двигуна або в циліндри двигунів внутрішнього зго- рання. Аналіз попередніх досліджень показав можливість отримання єдиної форми регре- сійної залежності для розрахунків розчинен- ня водню у рідких паливах. Обробка літера- турних даних та результатів власних дослі- джень дала сукупність регресійних рівнянь для розрахунку розчинності водню в рідких паливах: гасі, дизельному паливі, мазуті, LVGO, HVGO, GDAR, ABVB, Отримані ре- гресійні залежності показують, що з ростом середньої молекулярної маси палива розчин- ність водню в ньому знижується. Ці регре- сійні залежності дозволяють одержати вихід- ні дані для проектування паливних систем подачі паливо-водневих сумішей у камери mailto:recycle.lev@gmail.com Regression equations for calculating the solubility of hydrogen in liquid fuels ISSN 0041-6045. УКР . ХІМ . ЖУРН ., 2019, т . 85, No 12 115 згорання теплових машин. Дослідження на- сиченого воднем дизельного палива показа- ли зменшення температури початку спалаху на 10 – 15 оС порівняно з чистим паливом. Для тяжких палив такий рівень зменшення температури палива недостатній. Тому не- обхідно вести подальші дослідження по інте- нсифікації процесу розчинення водню в важ- ких паливах. Це значно знизить витрати ене- ргії на організацію процесу горіння палива. К л ю ч о в і с л о в а: водень, паливо, роз- чинність, регресійна залежність. РЕГРЕССИОННЫЕ УРАВНЕНИЯ ДЛЯ РАСЧЕТА РАСТВОРИМОСТИ ВОДОРОДА В ЖИДКИХ ТОПЛИВАХ Л.И.Лейбович*, Ю.В.Евстигнеев Национальный университет кораблестрое- ния имени адмирала Макарова, Николаев, просп. Героев Украины, 9, Николаев, 54025,Украина *e-mail: recycle.lev@gmail.com Эффективность горения жидких топлив в тепловых установках определяется прежде всего углеводородным составом топлива. От углеводородного топлива зависит скорость его горения и полнота сгорания. Поэтому ин- тенсификация процессов горения топлива является актуальной задачей повышения эф- фективности тепловых двигателей. Одним из путей повышения эффективности сгорания топлива является использование топливно- водородных смесей. Перспективным направ- лением создания таких смесей является пря- мое растворения водорода в жидком топливе. Это упрощает подачу топливно-водородной смеси в камеру сгорания теплового двигателя или в цилиндры ДВС. Анализ литературных данных и результатов собственных исследо- ваний показал возможность получения сово купности регрессионных уравнений для рас- чета растворимости водорода в жидких топ- ливах: керосине, дизельном топливе, мазуте, LVGO, HVGO, GDAR, ABVB, анализ полу- ченных регрессионной зависимости показал, что с ростом средней молекулярной массы топлива растворимость водорода в нем сни- жается. Полученные регрессионные зависи- мости позволяют получить исходные данные для проектирования топливных систем пода- чи топливно-водородных смей в тепловые машины. К л ю ч е в ы е с л о в а : водород, топливо, растворимость, регрессионная зависимость. REFERENCES 1. Bortnikov L.N., Rusakov M.M., Petrov R.E. Activation by hydrogen of the com- bustion of hydrocarbon fuels. Newsletter of sciences TSU. 2012. 4 (22): 137. [in Russian]. 2. Pavlov D.A., Bortnikov L.N. Research the performance engine at hydrogen additive in heterogeneous formation FAM. Newsletter of sciences TSU. 2012. 4 (22): 183. [in Russian]. 3. Novoselov S.V. Use of hydrogen as a mo- tor fuel. Thermal Engineering. 1996:27. [in Russian]. 4. Sirota A.A., Radchenko N.I., Shcherbak Yu.G. Profitabiliti of ship medium-speed diesel with application of small additives o f hydrogen to the diesel fuel, working accord- ing to the screw characteric. Aerospace technical and technology. 2014. 6 (113): 89. [in Russian]. 5. Gonigberg M.G. Chemical equilibrium and reaction rate at high pressures. M. Publish- ing House of the Academy of Sciences of the USSR. 1960. [in Russian]. 6. Vishnevsky N.E., Glukhanov N.P., Kovalev I.S. Machine and apparatus with a sealed mailto:recycle.lev@gmail.com L.I. Leybovych , Y.V.Yevstigneyev 116 ISSN 0041-6045. УКР . ХІМ . ЖУРН ., 2019, т . 85, No 12 electric drive. (Leningrad: Mechanical en- gineering,1977). 7. TorresI.R. , de Hemptinne J.-C., Machin I. Improving the Modeling of Hydrogen Solu- bility in Heavy Oil Cuts Using an Aug- mented Grayson Streed (AGS) Approach. Oil & Gas Science and Technology – Rev. IFP Energies nouvelles, 2013. 68(2):217. 8. Adrian A. Rodriguez Pinos. Modeling o f Hydrogen Consumption and Process Opti- mization for Hydrotreating of Light Gas Oils. (University of Saskatchewan, 2017). 9. Humberto Aguilar-Cisneros, Veronica Uribe-Vargas, Bernardo Carreon- Calderon, Jose Manuel Dominguez-Esquivel, Mario Ramirez de-Santiago Hydrogen Solubility in Heavy Undefined Petroleum Fractions Using Group. Contributions Methods. Oil & Gas Science and Technology – Rev. IFP Energies nouvelles. 2017. 72 (2): 11. 10. Leybovych L., Yevstigneyev Y.V. Solu- bility of hydrogen in mixtures of liquid fuels at atmospheric pressure. International periodic scientific journal. Modern engi- neering and innovative technologies. 2018. 3(5): 46.[in Russian]. 11. Sander R. Compilation of Henry's law constants (version 4.0) for water as sol- vent, Atmos. Chem. Phys. 2015 .15: 4399. 12. Sreven L. Jackrson. Extension of Wohl's ternary asymmetric solution model to four and n component. American Mineralogist. 1989. 74:1. 13. Conlisk A. Terrence. Essentials of Mi- cro- and Nanofluidics: With Applications to the Biological and Chemical Sciences. 2013. Cambridge University Press. 537. 14. Gladkaya A. V., Vinogradov O. L. En- tire functions of exponential type deviating least from zero with a weight. Abstracts of the international conference “Comlex anal- ysis & related topics”. St. Petersburg, 2014. 13, 15. Ru les for Construction of Power Boilers. ASME Boiler and Pressure Vessel Code. 2010. 341. . Received 25.11.2019 https://books.google.com/books?id=-fWeXMwX1x8C https://books.google.com/books?id=-fWeXMwX1x8C https://books.google.com/books?id=-fWeXMwX1x8C
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spelling oai:ojs2.1444248.nisspano.web.hosting-test.net:article-1082026-07-22T08:23:42Z REGRESSION EQUATIONS FOR CALCULATING THE SOLUBILITY OF HYDROGEN IN LIQUID FUELS РЕГРЕССИОННЫЕ УРАВНЕНИЯ ДЛЯ РАСЧЕТА РАСТВОРИМОСТИ ВОДОРОДА В ЖИДКИХ ТОПЛИВАХ РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРАХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ Leybovych, Lev Yevstigneyev, Yurii hydrogen, fuel, solubility, regression dependences. The efficiency of combustion of liquid fuels in heat engines is determined by their hydrocarbon composition. The rate of combustion and the completeness of combustion depend on  the  hydrocarbon composition of the fuel. One of the ways to increase the efficiency of combustion of fuel is to use fuel-hydrogen mixtures. The use of such mixtures gives prerequisites for low-temperature self-ignition of fuel droplets (about 590 °C). Preheating of the fuel gives the possibility of "explosive" combustion with increasing of the temperature up to 2500 K in 0.02 –. 0.04 ms. This leads to the intensification of heavy fuel combustion. The use of fuel-hydrogen mixtures allows to obtain a low level of harmful emissions with flue gases and to reduce emissions: CO and CH – not less than 15%, CO2 – not less than 20%. A promising direction for the creation of such mixtures is the direct dissolution of hydrogen in liquid fuel. This simplifies the flow of the fuel-hydrogen mixture into the combustion chamber of the heat engine or into the cylinders of the internal combustion engines. Analysis of previous studies showed the possibility of obtaining a single form of regression dependence for calculations of the dissolution of hydrogen in liquid fuels. The processing of the literature data and the results of our own research gave a set of regression equations for calculating the solubility of hydrogen in liquid fuels: gas, diesel, fuel oil, LVGO, HVGO, GDAR, ABVB. The obtained regression dependencies show that with increasing average molecular weight the solubility of hydrogen in the fuel decreases. These regression dependencies make it possible to obtain baseline data for the design of fuel systems for supplying fuel and hydrogen mixtures to combustion chambers of heat engines. Studies of hydrogen-diesel have shown a decrease in the flash fuel temperature by 10 – 15 oC by comparison with pure fuel. For heavy fuels, this level of reduction of the fuel round is not sufficient. Therefore, it is necessary to conduct further studies on the intensification of the process of dissolution of hydrogen in heavy fuels. This will significantly reduce energy costs for the organization of the combustion process. V.I.Vernadsky Institute of General and Inorganic Chemistry 2019-12-16 Article Article Physical chemistry Физическая xимия Фізична xімія application/pdf https://ucj.org.ua/index.php/journal/article/view/108 10.33609/0041-6045.85.11.2019.110-116 Ukrainian Chemistry Journal; Vol. 85 No. 12 (2019): Ukrainian Chemistry Journal; 110-116 Украинский химический журнал; ##issue.vol## 85 ##issue.no## 12 (2019): Украинский химический журнал; 110-116 Український хімічний журнал; Том 85 № 12 (2019): Український хімічний журнал; 110-116 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/108/72 Copyright (c) 2019 Lev Leybovych, Yurii Yevstigneyev https://creativecommons.org/licenses/by-nc/4.0
spellingShingle Leybovych, Lev
Yevstigneyev, Yurii
РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРАХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ
title РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРАХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ
title_alt REGRESSION EQUATIONS FOR CALCULATING THE SOLUBILITY OF HYDROGEN IN LIQUID FUELS
РЕГРЕССИОННЫЕ УРАВНЕНИЯ ДЛЯ РАСЧЕТА РАСТВОРИМОСТИ ВОДОРОДА В ЖИДКИХ ТОПЛИВАХ
title_full РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРАХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ
title_fullStr РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРАХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ
title_full_unstemmed РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРАХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ
title_short РЕГРЕСИВНІ РІВНЯННЯ ДЛЯ РОЗРАХУНКУ РОЗЧИННОСТІ ВОДНЮ В РІДКИХ ПАЛИВАХ
title_sort регресивні рівняння для розрахунку розчинності водню в рідких паливах
topic_facet hydrogen
fuel
solubility
regression dependences.
url https://ucj.org.ua/index.php/journal/article/view/108
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