СИНТЕЗ ТА СПЕКТРАЛЬНІ ХАРАКТЕРИСТИКИ КОМПЛЕКСІВ Ru(III,II), Rh(III) I Pd(II) З N-АЛІЛТІОАМІДАМИ І ПРОДУКТАМИ ЇХ ПРОТОНО- ТА ЙОДОЦИКЛІЗАЦІЇ

• Date: 2020
• Author Affiliations: Polina Borovyk — V.I. Vernadsky Institute of General and Inorganic Chemistry NAS of Ukraine; Mariia Litvinchuk — Organic Chemistry of the National Academy of Sciences of Ukraine; Anton Bentya — Organic Chemistry of the National Academy of Sciences of Ukraine; Svitlana Orysyk — V.I. Vernadsky Institute of General and Inorganic Chemistry NAS of Ukraine; Yuri Zborovskii — Institute of Organic Chemistry NAS of Ukraine; Viktor Orysyk — Institute of Organic Chemistry NAS of Ukraine; Vasyl Pekhnyo — V.I. Vernadsky Institute of General and Inorganic Chemistry NAS of Ukraine; Vovk Mykhailo — Institute of Organic Chemistry of the National Academic of Science of Ukraine
• Keywords: keywords
• Main Authors: Borovyk, Polina, Litvinchuk, Mariia, Bentya, Anton, Orysyk, Svitlana, Zborovskii, Yuri, Orysyk, Viktor, Pekhnyo, Vasyl, Mykhailo, Vovk
• Format: Article
• Language: English
• Published: V.I.Vernadsky Institute of General and Inorganic Chemistry 2020
• Online Access: https://ucj.org.ua/index.php/journal/article/view/145
• Journal Title: Ukrainian Chemistry Journal

The paper shows the possibility of using N-allylthioamides H2L1-H2L3 and products of their proton / iodine cyclization HL4, HL5 as chelating agents in the complexation reactions with Ru(III,II), Rh(III) and Pd(II) ions. As a result, a series of new chelating complexes of [M(HL1-3)Cl2(H2O)2], [M(HL1-...