СИНТЕЗ ТА ДІЕЛЕКТРИЧНІ ВЛАСТИВОСТІ КЕРАМІКИ La0,67LixTi1-xAlxO3

Solid solutions of Al-doped lithium lanthanum titanates La0.67LixTi1-xAlxO3 system (where 0.15 ≤ x ≤ 0.3) have been synthesized by solid-state reaction technique. Light optical microscopy has shown that the grain size of La0.67LixTi1-xAlxO3 ceramics insignificantl...

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Datum:2020
Hauptverfasser: Plutenko, Tatiana, V'yunov, Oleg, Khomenko, Boris, Belous, Anatolii
Format: Artikel
Sprache:English
Veröffentlicht: V.I.Vernadsky Institute of General and Inorganic Chemistry 2020
Online Zugang:https://ucj.org.ua/index.php/journal/article/view/254
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Назва журналу:Ukrainian Chemistry Journal

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Ukrainian Chemistry Journal
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Zusammenfassung:Solid solutions of Al-doped lithium lanthanum titanates La0.67LixTi1-xAlxO3 system (where 0.15 ≤ x ≤ 0.3) have been synthesized by solid-state reaction technique. Light optical microscopy has shown that the grain size of La0.67LixTi1-xAlxO3 ceramics insignificantly increases with an increase in lithium/aluminum concentration. The materials La0.67LixTi1-xAlxO3 show very high dielectric permittivity ε΄ 104 over a relatively wide frequency range (102 ≤ f ≤ 104 Hz) with no apparent dependence on the x. The impedance spectroscopy study indicates three semicircles on Cole-Cole diagram that can be attributed to electrically different areas of ceramic’s grain.