ЕЛЕКТРОПРОВІДНІСТЬ ТВЕРДИХ РОЗЧИНІВ Pb0,86‑xSmxSn1,14F4+x

• Date: 2021
• Author Affiliations: Yuliia Pohorenko — Vernadsky Institute of General and Inorganic Chemistry of National Academy of Sciences of Ukraine, 32-34 Aсademiс Palladin Avenue, Kyiv; Anatoliy Omel’chuk — Vernadsky Institute of General and Inorganic Chemistry of National Academy of Sciences of Ukraine, 32-34 Aсademiс Palladin Avenue, Kyiv; Anton Nagornyi — Vernadsky Institute of General and Inorganic Chemistry of National Academy of Sciences of Ukraine, 32-34 Aсademiс Palladin Avenue, Kyiv
• Keywords: keywords
• Main Authors: Pohorenko, Yuliia, Omel’chuk , Anatoliy, Nagornyi , Anton
• Format: Article
• Language: English
• Published: V.I.Vernadsky Institute of General and Inorganic Chemistry 2021
• Online Access: https://ucj.org.ua/index.php/journal/article/view/270
• Journal Title: Ukrainian Chemistry Journal

In the PbF2 – SmF3 – SnF2 system, he­tero­valent substitution solid solutions Pb0.86-xSmxSn1,14F4+x (0 < x ≤ 0.15) with the structure β-PbSnF4 are formed. The unit cell parameters of solid solutions are satisfactorily described by Vegard’s rules. The electrical conductivity of the obtaine...