СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ

Based on the screening of some heavy metals (HMs) content in the humus soil horizon of the Transcarpathian region, the regularities of the distribution of HMs in the soils of different landscape zones have been established. It is shown that  increasing of the terrain height, the content of...

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Datum:2021
Hauptverfasser: Sukharev , Sergii, Bugyna, Larysa, Pallah, Oleksandra, Sukhareva, Oksana, Drobnych, Volodymyr, Boyko, Nadiya
Format: Artikel
Sprache:English
Veröffentlicht: V.I.Vernadsky Institute of General and Inorganic Chemistry 2021
Online Zugang:https://ucj.org.ua/index.php/journal/article/view/280
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Назва журналу:Ukrainian Chemistry Journal

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Ukrainian Chemistry Journal
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spelling oai:ojs2.1444248.nisspano.web.hosting-test.net:article-2802021-03-26T10:29:25Z SCREENING OF THE CONTENT OF SOME HEAVY METALS AT THE HUMUS SOIL HORIZON OF THE TRANSCARPATHIAN REGION СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ Sukharev , Sergii Bugyna, Larysa Pallah, Oleksandra Sukhareva, Oksana Drobnych, Volodymyr Boyko, Nadiya geochemical features; gross content; acid-soluble form; migration coefficient. Based on the screening of some heavy metals (HMs) content in the humus soil horizon of the Transcarpathian region, the regularities of the distribution of HMs in the soils of different landscape zones have been established. It is shown that  increasing of the terrain height, the content of HMs in soils decreases (except for Mn and Hg) and for the total HMs content  the values of the Spearman correlation coefficient are: Cu – (-0.84); Zn – (-0.83); Mn 0.77; Mo – (-0.91); Co – (-0.82); Pb – (-0.83); Hg – absent; for the content of acid-soluble forms: Cu – absent; Zn – (-0.72); Mn 0.75; Mo – (-0.89); Co – (-0.86); Pb – (-0.77); Hg is absent. This pattern is associated with the tectonic and geological features of the different landscape zones. The calculation of the migration coefficient (the ratio of the content of acid-soluble forms to the gross content) has been shown that in mountainous regions this indicator has the highest value for Zn, Pb, and Cu. That means the potential danger of migration of these heavy me­tals and their bioavailability. This is probably connected to the type of soil in the mountai­nous areas of the region. A pronounced inter-element correlation of the HMs content in soils (except for Hg) has been established and the corresponding values of Pearson’s coefficients for the gross content are: Cu:Zn – 0,96; Cu:Mn – (-0,84); Cu:Mo – 0,89; Cu:Co – 0,99; Cu:Pb – 0,87; Zn:Mn – (-0,79); Zn:Mo – 0,91; Zn:Co – 0,96; Zn:Pb – 0,86; Mn:Mo – (-0,86); Mn:Co – (-0,84); Mn:Pb – (-0,75); Mo:Co – 0,87; Mo:Pb – 0,81; Co:Pb – 0,87. This makes it possible to predict the content of several HMs in the soils of the Transcarpathian region based on the results of determining one of them. In general, the content of HMs in the humus soil horizon (total content and content of mobile forms) is lower than the corresponding values of maximum permissible concentrations.   V.I.Vernadsky Institute of General and Inorganic Chemistry 2021-03-19 Article Article Physical chemistry Физическая xимия Фізична xімія application/pdf https://ucj.org.ua/index.php/journal/article/view/280 10.33609/2708-129X.87.02.2021.107-116 Ukrainian Chemistry Journal; Vol 87 No 2 (2021): Ukrainian Chemistry Journal; 107-116 Украинский химический журнал; Том 87 № 2 (2021): Украинский химический журнал; 107-116 Український хімічний журнал; Том 87 № 2 (2021): Український хімічний журнал; 107-116 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/280/157
institution Ukrainian Chemistry Journal
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datestamp_date 2021-03-26T10:29:25Z
collection OJS
language English
topic_facet geochemical features
gross content
acid-soluble form
migration coefficient.
format Article
author Sukharev , Sergii
Bugyna, Larysa
Pallah, Oleksandra
Sukhareva, Oksana
Drobnych, Volodymyr
Boyko, Nadiya
spellingShingle Sukharev , Sergii
Bugyna, Larysa
Pallah, Oleksandra
Sukhareva, Oksana
Drobnych, Volodymyr
Boyko, Nadiya
СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ
author_facet Sukharev , Sergii
Bugyna, Larysa
Pallah, Oleksandra
Sukhareva, Oksana
Drobnych, Volodymyr
Boyko, Nadiya
author_sort Sukharev , Sergii
title СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ
title_short СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ
title_full СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ
title_fullStr СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ
title_full_unstemmed СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ
title_sort скринінг вмісту деяких важких металів у гумусовому ґрунтовому горизонті закарпатської області
title_alt SCREENING OF THE CONTENT OF SOME HEAVY METALS AT THE HUMUS SOIL HORIZON OF THE TRANSCARPATHIAN REGION
description Based on the screening of some heavy metals (HMs) content in the humus soil horizon of the Transcarpathian region, the regularities of the distribution of HMs in the soils of different landscape zones have been established. It is shown that  increasing of the terrain height, the content of HMs in soils decreases (except for Mn and Hg) and for the total HMs content  the values of the Spearman correlation coefficient are: Cu – (-0.84); Zn – (-0.83); Mn 0.77; Mo – (-0.91); Co – (-0.82); Pb – (-0.83); Hg – absent; for the content of acid-soluble forms: Cu – absent; Zn – (-0.72); Mn 0.75; Mo – (-0.89); Co – (-0.86); Pb – (-0.77); Hg is absent. This pattern is associated with the tectonic and geological features of the different landscape zones. The calculation of the migration coefficient (the ratio of the content of acid-soluble forms to the gross content) has been shown that in mountainous regions this indicator has the highest value for Zn, Pb, and Cu. That means the potential danger of migration of these heavy me­tals and their bioavailability. This is probably connected to the type of soil in the mountai­nous areas of the region. A pronounced inter-element correlation of the HMs content in soils (except for Hg) has been established and the corresponding values of Pearson’s coefficients for the gross content are: Cu:Zn – 0,96; Cu:Mn – (-0,84); Cu:Mo – 0,89; Cu:Co – 0,99; Cu:Pb – 0,87; Zn:Mn – (-0,79); Zn:Mo – 0,91; Zn:Co – 0,96; Zn:Pb – 0,86; Mn:Mo – (-0,86); Mn:Co – (-0,84); Mn:Pb – (-0,75); Mo:Co – 0,87; Mo:Pb – 0,81; Co:Pb – 0,87. This makes it possible to predict the content of several HMs in the soils of the Transcarpathian region based on the results of determining one of them. In general, the content of HMs in the humus soil horizon (total content and content of mobile forms) is lower than the corresponding values of maximum permissible concentrations.  
publisher V.I.Vernadsky Institute of General and Inorganic Chemistry
publishDate 2021
url https://ucj.org.ua/index.php/journal/article/view/280
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last_indexed 2025-09-24T17:43:37Z
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