СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ
Based on the screening of some heavy metals (HMs) content in the humus soil horizon of the Transcarpathian region, the regularities of the distribution of HMs in the soils of different landscape zones have been established. It is shown that increasing of the terrain height, the content of...
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V.I.Vernadsky Institute of General and Inorganic Chemistry
2021
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oai:ojs2.1444248.nisspano.web.hosting-test.net:article-2802021-03-26T10:29:25Z SCREENING OF THE CONTENT OF SOME HEAVY METALS AT THE HUMUS SOIL HORIZON OF THE TRANSCARPATHIAN REGION СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ Sukharev , Sergii Bugyna, Larysa Pallah, Oleksandra Sukhareva, Oksana Drobnych, Volodymyr Boyko, Nadiya geochemical features; gross content; acid-soluble form; migration coefficient. Based on the screening of some heavy metals (HMs) content in the humus soil horizon of the Transcarpathian region, the regularities of the distribution of HMs in the soils of different landscape zones have been established. It is shown that increasing of the terrain height, the content of HMs in soils decreases (except for Mn and Hg) and for the total HMs content the values of the Spearman correlation coefficient are: Cu – (-0.84); Zn – (-0.83); Mn 0.77; Mo – (-0.91); Co – (-0.82); Pb – (-0.83); Hg – absent; for the content of acid-soluble forms: Cu – absent; Zn – (-0.72); Mn 0.75; Mo – (-0.89); Co – (-0.86); Pb – (-0.77); Hg is absent. This pattern is associated with the tectonic and geological features of the different landscape zones. The calculation of the migration coefficient (the ratio of the content of acid-soluble forms to the gross content) has been shown that in mountainous regions this indicator has the highest value for Zn, Pb, and Cu. That means the potential danger of migration of these heavy metals and their bioavailability. This is probably connected to the type of soil in the mountainous areas of the region. A pronounced inter-element correlation of the HMs content in soils (except for Hg) has been established and the corresponding values of Pearson’s coefficients for the gross content are: Cu:Zn – 0,96; Cu:Mn – (-0,84); Cu:Mo – 0,89; Cu:Co – 0,99; Cu:Pb – 0,87; Zn:Mn – (-0,79); Zn:Mo – 0,91; Zn:Co – 0,96; Zn:Pb – 0,86; Mn:Mo – (-0,86); Mn:Co – (-0,84); Mn:Pb – (-0,75); Mo:Co – 0,87; Mo:Pb – 0,81; Co:Pb – 0,87. This makes it possible to predict the content of several HMs in the soils of the Transcarpathian region based on the results of determining one of them. In general, the content of HMs in the humus soil horizon (total content and content of mobile forms) is lower than the corresponding values of maximum permissible concentrations. V.I.Vernadsky Institute of General and Inorganic Chemistry 2021-03-19 Article Article Physical chemistry Физическая xимия Фізична xімія application/pdf https://ucj.org.ua/index.php/journal/article/view/280 10.33609/2708-129X.87.02.2021.107-116 Ukrainian Chemistry Journal; Vol 87 No 2 (2021): Ukrainian Chemistry Journal; 107-116 Украинский химический журнал; Том 87 № 2 (2021): Украинский химический журнал; 107-116 Український хімічний журнал; Том 87 № 2 (2021): Український хімічний журнал; 107-116 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/280/157 |
| institution |
Ukrainian Chemistry Journal |
| baseUrl_str |
|
| datestamp_date |
2021-03-26T10:29:25Z |
| collection |
OJS |
| language |
English |
| topic_facet |
geochemical features gross content acid-soluble form migration coefficient. |
| format |
Article |
| author |
Sukharev , Sergii Bugyna, Larysa Pallah, Oleksandra Sukhareva, Oksana Drobnych, Volodymyr Boyko, Nadiya |
| spellingShingle |
Sukharev , Sergii Bugyna, Larysa Pallah, Oleksandra Sukhareva, Oksana Drobnych, Volodymyr Boyko, Nadiya СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ |
| author_facet |
Sukharev , Sergii Bugyna, Larysa Pallah, Oleksandra Sukhareva, Oksana Drobnych, Volodymyr Boyko, Nadiya |
| author_sort |
Sukharev , Sergii |
| title |
СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ |
| title_short |
СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ |
| title_full |
СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ |
| title_fullStr |
СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ |
| title_full_unstemmed |
СКРИНІНГ ВМІСТУ ДЕЯКИХ ВАЖКИХ МЕТАЛІВ У ГУМУСОВОМУ ҐРУНТОВОМУ ГОРИЗОНТІ ЗАКАРПАТСЬКОЇ ОБЛАСТІ |
| title_sort |
скринінг вмісту деяких важких металів у гумусовому ґрунтовому горизонті закарпатської області |
| title_alt |
SCREENING OF THE CONTENT OF SOME HEAVY METALS AT THE HUMUS SOIL HORIZON OF THE TRANSCARPATHIAN REGION |
| description |
Based on the screening of some heavy metals (HMs) content in the humus soil horizon of the Transcarpathian region, the regularities of the distribution of HMs in the soils of different landscape zones have been established. It is shown that increasing of the terrain height, the content of HMs in soils decreases (except for Mn and Hg) and for the total HMs content the values of the Spearman correlation coefficient are: Cu – (-0.84); Zn – (-0.83); Mn 0.77; Mo – (-0.91); Co – (-0.82); Pb – (-0.83); Hg – absent; for the content of acid-soluble forms: Cu – absent; Zn – (-0.72); Mn 0.75; Mo – (-0.89); Co – (-0.86); Pb – (-0.77); Hg is absent. This pattern is associated with the tectonic and geological features of the different landscape zones. The calculation of the migration coefficient (the ratio of the content of acid-soluble forms to the gross content) has been shown that in mountainous regions this indicator has the highest value for Zn, Pb, and Cu. That means the potential danger of migration of these heavy metals and their bioavailability. This is probably connected to the type of soil in the mountainous areas of the region. A pronounced inter-element correlation of the HMs content in soils (except for Hg) has been established and the corresponding values of Pearson’s coefficients for the gross content are: Cu:Zn – 0,96; Cu:Mn – (-0,84); Cu:Mo – 0,89; Cu:Co – 0,99; Cu:Pb – 0,87; Zn:Mn – (-0,79); Zn:Mo – 0,91; Zn:Co – 0,96; Zn:Pb – 0,86; Mn:Mo – (-0,86); Mn:Co – (-0,84); Mn:Pb – (-0,75); Mo:Co – 0,87; Mo:Pb – 0,81; Co:Pb – 0,87. This makes it possible to predict the content of several HMs in the soils of the Transcarpathian region based on the results of determining one of them. In general, the content of HMs in the humus soil horizon (total content and content of mobile forms) is lower than the corresponding values of maximum permissible concentrations.
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| publisher |
V.I.Vernadsky Institute of General and Inorganic Chemistry |
| publishDate |
2021 |
| url |
https://ucj.org.ua/index.php/journal/article/view/280 |
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