КООРДИНАЦІЙНІ СПОЛУКИ Gd3+ та Dy3+ З ДЕЯКИМИ β-ДИКЕТОНАМИ
New complexes of Dy (III) and Gd (III) with b-diketones containing unsaturated and aryl substituents were synthesized. Metal polymers based on synthesized complexes were obtained by the method of radical polymerization. The composition and structure of synthesized complexes and metal polymers are es...
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| Date: | 2021 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Published: |
V.I.Vernadsky Institute of General and Inorganic Chemistry
2021
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| Online Access: | https://ucj.org.ua/index.php/journal/article/view/324 |
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| Journal Title: | Ukrainian Chemistry Journal |
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Ukrainian Chemistry Journal| Summary: | New complexes of Dy (III) and Gd (III) with b-diketones containing unsaturated and aryl substituents were synthesized. Metal polymers based on synthesized complexes were obtained by the method of radical polymerization. The composition and structure of synthesized complexes and metal polymers are established. It is shown that during polymerization the coordination environment of the central ion remains unchanged. The spectral-luminescent characteristics of the synthesized compounds were studied. The presence of water molecules in the immediate coordination environment causes a low intensity of emission of monomeric dysprosium complexes. In the luminescence spectra of metal polymers, there are bands magnetic dipole transition (4F9 → 6H15/2) and electric dipole transition (4F9 → 6H13/2). The close energies of the triplet level of the ligand and the resonant level of the dysprosium ion cause low emission characteristics of the synthesized dysprosium complexes. |
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