SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS
Development of micro- and nanosized spin-crossover (SCO) materials has become an important research direction within the past decade. Such an interest is associated with high perceptive of practical application of these materials in nanoelectronic devices. Therefore, researches working in the field...
Збережено в:
| Дата: | 2021 |
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| Автори: | , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
V.I.Vernadsky Institute of General and Inorganic Chemistry
2021
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| Онлайн доступ: | https://ucj.org.ua/index.php/journal/article/view/379 |
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| Назва журналу: | Ukrainian Chemistry Journal |
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oai:ojs2.1444248.nisspano.web.hosting-test.net:article-3792022-01-10T10:53:19Z SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS Hiiuk, Volodymyr Suleimanov, Iurii Fritsky, Igor spin crossover, Fe(II) coordination compounds, luminescent devices, nanoelectronic devices, micromechanical constructions. Development of micro- and nanosized spin-crossover (SCO) materials has become an important research direction within the past decade. Such an interest is associated with high perceptive of practical application of these materials in nanoelectronic devices. Therefore, researches working in the field of SCO put considerable efforts to obtain SCO complexes in various functional forms, such as nanoparticles, thin films, etc. Fabrication of these materials is realized through different chemical and/or lithographical approaches, which allow to adjust size, shape and even organization of nanoobjects. In this review theoretical background of SCO phenomenon is described, additionally different classes of coordination compounds exhibiting spin crossover are covered. It is demonstrated that electric field, temperature and light irradiation can be effectively used for switching and control of spin state in nanosized SCO systems. Cooperative SCO with transition close to room temperature, wide hysteresis loop and distinct thermochromic effect is most often observed for Fe(II) coordination complexes. Therefore, Fe(II) SCO compounds form one of the most perspective classes of compounds for obtaining functional materials. It is shown that integration of Fe(II) compounds into micro- and nanohybrid devices allows to combine unique functional properties in one material due to synergy between SCO and physical properties (luminescent, electrical, etc.) of the other component. As a result, SCO compounds are interesting not only from the fundamental point of view, but also from practical, thanks to the possibility of integration of SCO Fe(II) complexes as active materials in devices of different configurations. It is expected that obtaining of new Fe(II) coordination polymers with unique SCO characteristics will favor the development of new functional materials and devices on their basis in the nearest future. V.I.Vernadsky Institute of General and Inorganic Chemistry 2021-12-24 Article Article Inorganic Chemistry Неорганическая химия Неорганічна хімія application/pdf https://ucj.org.ua/index.php/journal/article/view/379 10.33609/2708-129X.87.11.2021.3-20 Ukrainian Chemistry Journal; Vol. 87 No. 11 (2021): Ukrainian Chemistry Journal; 3-20 Украинский химический журнал; Том 87 № 11 (2021): Ukrainian Chemistry Journal; 3-20 Український хімічний журнал; Том 87 № 11 (2021): Український хімічний журнал; 3-20 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/379/200 |
| institution |
Ukrainian Chemistry Journal |
| baseUrl_str |
|
| datestamp_date |
2022-01-10T10:53:19Z |
| collection |
OJS |
| language |
English |
| topic_facet |
spin crossover Fe(II) coordination compounds luminescent devices nanoelectronic devices micromechanical constructions. |
| format |
Article |
| author |
Hiiuk, Volodymyr Suleimanov, Iurii Fritsky, Igor |
| spellingShingle |
Hiiuk, Volodymyr Suleimanov, Iurii Fritsky, Igor SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS |
| author_facet |
Hiiuk, Volodymyr Suleimanov, Iurii Fritsky, Igor |
| author_sort |
Hiiuk, Volodymyr |
| title |
SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS |
| title_short |
SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS |
| title_full |
SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS |
| title_fullStr |
SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS |
| title_full_unstemmed |
SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS |
| title_sort |
spin-crossover iron(ii) coordination compounds: fabrication of functional materials and their integration into micro- and nanoconstructions |
| description |
Development of micro- and nanosized spin-crossover (SCO) materials has become an important research direction within the past decade. Such an interest is associated with high perceptive of practical application of these materials in nanoelectronic devices. Therefore, researches working in the field of SCO put considerable efforts to obtain SCO complexes in various functional forms, such as nanoparticles, thin films, etc. Fabrication of these materials is realized through different chemical and/or lithographical approaches, which allow to adjust size, shape and even organization of nanoobjects.
In this review theoretical background of SCO phenomenon is described, additionally different classes of coordination compounds exhibiting spin crossover are covered. It is demonstrated that electric field, temperature and light irradiation can be effectively used for switching and control of spin state in nanosized SCO systems. Cooperative SCO with transition close to room temperature, wide hysteresis loop and distinct thermochromic effect is most often observed for Fe(II) coordination complexes. Therefore, Fe(II) SCO compounds form one of the most perspective classes of compounds for obtaining functional materials. It is shown that integration of Fe(II) compounds into micro- and nanohybrid devices allows to combine unique functional properties in one material due to synergy between SCO and physical properties (luminescent, electrical, etc.) of the other component. As a result, SCO compounds are interesting not only from the fundamental point of view, but also from practical, thanks to the possibility of integration of SCO Fe(II) complexes as active materials in devices of different configurations.
It is expected that obtaining of new Fe(II) coordination polymers with unique SCO characteristics will favor the development of new functional materials and devices on their basis in the nearest future. |
| publisher |
V.I.Vernadsky Institute of General and Inorganic Chemistry |
| publishDate |
2021 |
| url |
https://ucj.org.ua/index.php/journal/article/view/379 |
| work_keys_str_mv |
AT hiiukvolodymyr spincrossoverironiicoordinationcompoundsfabricationoffunctionalmaterialsandtheirintegrationintomicroandnanoconstructions AT suleimanoviurii spincrossoverironiicoordinationcompoundsfabricationoffunctionalmaterialsandtheirintegrationintomicroandnanoconstructions AT fritskyigor spincrossoverironiicoordinationcompoundsfabricationoffunctionalmaterialsandtheirintegrationintomicroandnanoconstructions |
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2025-09-24T17:43:42Z |
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2025-09-24T17:43:42Z |
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