CATALYSIS OF HYDRODEHALOGENATION RE­ACTION OF HALOARENES BY CARBENE PEPPSI-PALLADIUM COMPLEXES

• Date: 2022
• Author Affiliations: Vagiz Saberov — Institute of Organic Chemistry, NASU; Alexander Avksentiev — Institute of Organic Chemistry, NASU; Gennady Rayenko — The L.M.Litvinenko Institute of Physical Organic and Coal Chemistry, NASU; Alexey Ryabitsky — Life chemicals Inc.; Vasil Yenya — Institute of Organic Chemistry, NASU; Maxim Nechitaylov — The L.M.Litvinenko Institute of Physical Organic and Coal Chemistry, NASU; Nikolai Korotkikh — Institute of Organic Chemistry, NASU
• Keywords: keywords
• Main Authors: Saberov , Vagiz, Avksentiev, Alexander, Rayenko, Gennady, Ryabitsky , Alexey, Yenya , Vasil, Nechitaylov , Maxim, Korotkikh , Nikolai
• Format: Article
• Language: English
• Published: V.I.Vernadsky Institute of General and Inorganic Chemistry 2022
• Online Access: https://ucj.org.ua/index.php/journal/article/view/401
• Journal Title: Ukrainian Chemistry Journal

The synthesis of a number of carbene PEPPSI-complexes of palladium with various pyridine and carbene ligands was carried out by reactions of 1,3-bis-(2,6-dibenzhydryl-4-methyl­phenyl)imidazolium chloride IPr*.HCl [compounds 7a-c IPr*PdCl2L’, L’ = pyridine (а), 3-chloropyridine (b), 4-dimethylaminopy...