INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3

The peculiarities of formation and properties of organiс-inorganic MAPbI3 perovskite films, obtained from solutions with different ratios of starting reagents (PbI2:MAI = 1:1,1:2, and 1:3), in the DMF and DMSO solvents, studied. As the PbI2:MAI ratio increases, the temperature of the formation of a...

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Datum:2022
Hauptverfasser: Torchyniuk, Pavlo, V'yunov, Oleg, Vlasyuk, Viktor, Kostylyov, Vitaliy, Belous, Anatolii
Format: Artikel
Sprache:English
Veröffentlicht: V.I.Vernadsky Institute of General and Inorganic Chemistry 2022
Online Zugang:https://ucj.org.ua/index.php/journal/article/view/434
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Назва журналу:Ukrainian Chemistry Journal

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Ukrainian Chemistry Journal
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spelling oai:ojs2.1444248.nisspano.web.hosting-test.net:article-4342022-07-06T15:58:46Z INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3 Torchyniuk, Pavlo V'yunov, Oleg Vlasyuk, Viktor Kostylyov, Vitaliy Belous, Anatolii organic-inorganic perovskite, phase transformations, structural parameters, electrophysical characteristics. The peculiarities of formation and properties of organiс-inorganic MAPbI3 perovskite films, obtained from solutions with different ratios of starting reagents (PbI2:MAI = 1:1,1:2, and 1:3), in the DMF and DMSO solvents, studied. As the PbI2:MAI ratio increases, the temperature of the formation of a single-phase MAPbI3 perovskite film also increases. The slight changes in the structural and electrophysical characteristics for perovskite films obtained at the  different ratios of PbI2:MAI in DMF and DMSO were found. These changes are related to the solvent that is included in the crystalline structure of perovskite. In the same ratios of starting reagents, DMF is included in the structure of perovskite in a greater amount than DMSO. V.I.Vernadsky Institute of General and Inorganic Chemistry 2022-05-25 Article Article Inorganic Chemistry Неорганическая химия Неорганічна хімія application/pdf https://ucj.org.ua/index.php/journal/article/view/434 10.33609/2708-129X.88.04.2022.79-93 Ukrainian Chemistry Journal; Vol. 88 No. 4 (2022): Ukrainian Chemistry Journal; 79-93 Украинский химический журнал; Том 88 № 4 (2022): Ukrainian Chemistry Journal; 79-93 Український хімічний журнал; Том 88 № 4 (2022): Український хімічний журнал; 79-93 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/434/222
institution Ukrainian Chemistry Journal
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datestamp_date 2022-07-06T15:58:46Z
collection OJS
language English
topic_facet organic-inorganic perovskite
phase transformations
structural parameters
electrophysical characteristics.
format Article
author Torchyniuk, Pavlo
V'yunov, Oleg
Vlasyuk, Viktor
Kostylyov, Vitaliy
Belous, Anatolii
spellingShingle Torchyniuk, Pavlo
V'yunov, Oleg
Vlasyuk, Viktor
Kostylyov, Vitaliy
Belous, Anatolii
INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3
author_facet Torchyniuk, Pavlo
V'yunov, Oleg
Vlasyuk, Viktor
Kostylyov, Vitaliy
Belous, Anatolii
author_sort Torchyniuk, Pavlo
title INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3
title_short INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3
title_full INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3
title_fullStr INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3
title_full_unstemmed INFLUENCE OF THE SOLVENT AND THE RATIO OF STARTING REAGENTS ON THE PROPERTIES OF ORGANIC-INORGANIC PEROVSKITE MAPbI3
title_sort influence of the solvent and the ratio of starting reagents on the properties of organic-inorganic perovskite mapbi3
description The peculiarities of formation and properties of organiс-inorganic MAPbI3 perovskite films, obtained from solutions with different ratios of starting reagents (PbI2:MAI = 1:1,1:2, and 1:3), in the DMF and DMSO solvents, studied. As the PbI2:MAI ratio increases, the temperature of the formation of a single-phase MAPbI3 perovskite film also increases. The slight changes in the structural and electrophysical characteristics for perovskite films obtained at the  different ratios of PbI2:MAI in DMF and DMSO were found. These changes are related to the solvent that is included in the crystalline structure of perovskite. In the same ratios of starting reagents, DMF is included in the structure of perovskite in a greater amount than DMSO.
publisher V.I.Vernadsky Institute of General and Inorganic Chemistry
publishDate 2022
url https://ucj.org.ua/index.php/journal/article/view/434
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first_indexed 2025-09-24T17:43:44Z
last_indexed 2025-09-24T17:43:44Z
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