SYNTHESIS AND COMPLEX-FORMING PRO­PERTIES OF THIO-CONTAINING COMPLEXONS: S,S'- ETHYLENEDITHIODIALANINE AND S,S'- CARBOXY- ETHYLENEDITHIODIALANINE

• Date: 2022
• Author Affiliations: Elena Trunova — V. I. Vernadskii Institute of General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Akad. Palladin Avenue 32/34, Kyiv 03142, Ukraine; Ganna Artamonova — Kyiv Scientific Research Institute of Forensic Expertise of the Ministry of Justice of Ukraine, 6 St. The Brodsky family Street, 03057 Kyiv, Ukraine; Mariya Rusakova — Odessa I.I. Mechnikov National University; Oleksei Vasin — V. I. Vernadskii Institute of General and Inorganic Chemistry of the Ukrainian National Academy of Sciences, Akad. Palladin Avenue 32/34, Kyiv 03142, Ukraine; Vladimir Glushakov — V.I. Vernadsky Institute of General and Inorganic Chemistry NAS of Ukraine
• Keywords: keywords
• Main Authors: Trunova , Elena, Artamonova, Ganna, Rusakova, Mariya, Vasin, Oleksei, Glushakov, Vladimir
• Format: Article
• Language: English
• Published: V.I.Vernadsky Institute of General and Inorganic Chemistry 2022
• Online Access: https://ucj.org.ua/index.php/journal/article/view/494
• Journal Title: Ukrainian Chemistry Journal

Two thio-containing complexones – S,S'-ethy­lenedithiodialanin (EDAL) and S,S'-carboxy-ethylenedithiodialanin (СEDAL) – were synthesized by the alkylation reaction of L-cysteine with dibromoethane. The developed technique has a number of advantages compared to those described in the litera...