ELECTROCHEMICAL BIOSENSORS FOR CONT­ROL OF LEAD CONTENT IN THE ENVIRONMENT. A REVIEW

The review presents different types of biosensors and their principles of operation that are currently used to detect heavy metals and lead. Biosensors are considered highly sensitive, specific, accurate, inexpensive and effective tools for the preliminary detection of one or more metals in sources...

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Бібліографічні деталі
Дата:2022
Автори: Zinko, Lionel, Pletenets, Yelyzaveta
Формат: Стаття
Мова:English
Опубліковано: V.I.Vernadsky Institute of General and Inorganic Chemistry 2022
Онлайн доступ:https://ucj.org.ua/index.php/journal/article/view/496
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Назва журналу:Ukrainian Chemistry Journal

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Ukrainian Chemistry Journal
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spelling oai:ojs2.1444248.nisspano.web.hosting-test.net:article-4962023-02-07T11:55:39Z ELECTROCHEMICAL BIOSENSORS FOR CONT­ROL OF LEAD CONTENT IN THE ENVIRONMENT. A REVIEW Zinko, Lionel Pletenets, Yelyzaveta electrochemical biosensors, lead, modification, metal-organic frameworks, layered double hydroxides. The review presents different types of biosensors and their principles of operation that are currently used to detect heavy metals and lead. Biosensors are considered highly sensitive, specific, accurate, inexpensive and effective tools for the preliminary detection of one or more metals in sources of mixed pollution, especially in wastewater. The use of functional nanomaterials based on metal-organic frameworks and layered hydroxides allowed to miniaturize the design of biosensors and significantly improve their applicability for on-site analysis of target samples, which reduces the probability of any changes in the samples during transport to the laboratory. Also, these materials have long-term stability, improve the signal and response speed of electrochemical biosensors, and also increase their sensitivity and selectivity. An overview of the methods of manufacturing the active component of multilayer electrochemical sensors was conducted. The main methods of obtaining stable and sensitive to lead ions electrochemical systems are noted.Sensors and biosensors are powerful tools for accurate qualitative and quantitative analysis of a specific analyte and integration of biotechnology, microelectronics, and nanotechnology to fabricate miniaturized devices without loss of sensitivity, specificity, and cont­rol accuracy. The characteristic properties of biomolecule carriers significantly affect the sensitivity and selectivity of the device. The impact of carriers based on metal-organic frameworks and layered hydroxides on increasing the efficiency of modern lead biosensors due to the implementation of the enzyme inhibition mechanism was considered, and the me­thods of manufacturing the active component of multilayer electrochemical sensors were also reviewed. The perspective of using the coprecipitation method and the ion exchange method to obtain stable and sensitive lead ion electrochemical systems was noted. Thus, electrochemical biosensors can be considered as one of the most widely developed biosensors for the detection of lead ions, in which the presence of direct electron transfer from the recognition center to the electrode reduces the probability of unnecessary interference, which significantly increases their sensitivity and selectivity and enables the development of devices for in-mode monitoring real-time. V.I.Vernadsky Institute of General and Inorganic Chemistry 2022-12-23 Article Article Physical chemistry Физическая xимия Фізична xімія application/pdf https://ucj.org.ua/index.php/journal/article/view/496 10.33609/2708-129X.88.11.2022.55-87 Ukrainian Chemistry Journal; Vol 88 No 11 (2022): Ukrainian Chemistry Journal; 55-87 Украинский химический журнал; Том 88 № 11 (2022): Ukrainian Chemistry Journal; 55-87 Український хімічний журнал; Том 88 № 11 (2022): Український хімічний журнал; 55-87 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/496/256
institution Ukrainian Chemistry Journal
baseUrl_str
datestamp_date 2023-02-07T11:55:39Z
collection OJS
language English
topic_facet electrochemical biosensors
lead
modification
metal-organic frameworks
layered double hydroxides.
format Article
author Zinko, Lionel
Pletenets, Yelyzaveta
spellingShingle Zinko, Lionel
Pletenets, Yelyzaveta
ELECTROCHEMICAL BIOSENSORS FOR CONT­ROL OF LEAD CONTENT IN THE ENVIRONMENT. A REVIEW
author_facet Zinko, Lionel
Pletenets, Yelyzaveta
author_sort Zinko, Lionel
title ELECTROCHEMICAL BIOSENSORS FOR CONT­ROL OF LEAD CONTENT IN THE ENVIRONMENT. A REVIEW
title_short ELECTROCHEMICAL BIOSENSORS FOR CONT­ROL OF LEAD CONTENT IN THE ENVIRONMENT. A REVIEW
title_full ELECTROCHEMICAL BIOSENSORS FOR CONT­ROL OF LEAD CONTENT IN THE ENVIRONMENT. A REVIEW
title_fullStr ELECTROCHEMICAL BIOSENSORS FOR CONT­ROL OF LEAD CONTENT IN THE ENVIRONMENT. A REVIEW
title_full_unstemmed ELECTROCHEMICAL BIOSENSORS FOR CONT­ROL OF LEAD CONTENT IN THE ENVIRONMENT. A REVIEW
title_sort electrochemical biosensors for cont­rol of lead content in the environment. a review
description The review presents different types of biosensors and their principles of operation that are currently used to detect heavy metals and lead. Biosensors are considered highly sensitive, specific, accurate, inexpensive and effective tools for the preliminary detection of one or more metals in sources of mixed pollution, especially in wastewater. The use of functional nanomaterials based on metal-organic frameworks and layered hydroxides allowed to miniaturize the design of biosensors and significantly improve their applicability for on-site analysis of target samples, which reduces the probability of any changes in the samples during transport to the laboratory. Also, these materials have long-term stability, improve the signal and response speed of electrochemical biosensors, and also increase their sensitivity and selectivity. An overview of the methods of manufacturing the active component of multilayer electrochemical sensors was conducted. The main methods of obtaining stable and sensitive to lead ions electrochemical systems are noted.Sensors and biosensors are powerful tools for accurate qualitative and quantitative analysis of a specific analyte and integration of biotechnology, microelectronics, and nanotechnology to fabricate miniaturized devices without loss of sensitivity, specificity, and cont­rol accuracy. The characteristic properties of biomolecule carriers significantly affect the sensitivity and selectivity of the device. The impact of carriers based on metal-organic frameworks and layered hydroxides on increasing the efficiency of modern lead biosensors due to the implementation of the enzyme inhibition mechanism was considered, and the me­thods of manufacturing the active component of multilayer electrochemical sensors were also reviewed. The perspective of using the coprecipitation method and the ion exchange method to obtain stable and sensitive lead ion electrochemical systems was noted. Thus, electrochemical biosensors can be considered as one of the most widely developed biosensors for the detection of lead ions, in which the presence of direct electron transfer from the recognition center to the electrode reduces the probability of unnecessary interference, which significantly increases their sensitivity and selectivity and enables the development of devices for in-mode monitoring real-time.
publisher V.I.Vernadsky Institute of General and Inorganic Chemistry
publishDate 2022
url https://ucj.org.ua/index.php/journal/article/view/496
work_keys_str_mv AT zinkolionel electrochemicalbiosensorsforcontrolofleadcontentintheenvironmentareview
AT pletenetsyelyzaveta electrochemicalbiosensorsforcontrolofleadcontentintheenvironmentareview
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