DEVELOPMENT OF SORPTION MATERIALS OF WIDE FUNCTIONAL PURPOSE IN THE V.I. VERNADSKII INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY OF THE NAS OF UKRAINE

The review is devoted to the work, which were performed at the V.I. Vernadskii Institute of General and Inorganic Chemistry of the NAS of Ukraine according to the direction of the development of sorption naterials of wide functional purpose. All sorbents can be used in separation processes: due to t...

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Date:2023
Main Authors: Maltseva, Tetiana, Dzyazko, Yulliya
Format: Article
Language:English
Published: V.I.Vernadsky Institute of General and Inorganic Chemistry 2023
Online Access:https://ucj.org.ua/index.php/journal/article/view/506
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Journal Title:Ukrainian Chemistry Journal

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Ukrainian Chemistry Journal
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spelling oai:ojs2.1444248.nisspano.web.hosting-test.net:article-5062023-03-22T13:10:11Z DEVELOPMENT OF SORPTION MATERIALS OF WIDE FUNCTIONAL PURPOSE IN THE V.I. VERNADSKII INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY OF THE NAS OF UKRAINE Maltseva, Tetiana Dzyazko, Yulliya sorbents, composites, hydrophosphates of multivalent metals, hydrated doubleoxides, ion exchangeresins The review is devoted to the work, which were performed at the V.I. Vernadskii Institute of General and Inorganic Chemistry of the NAS of Ukraine according to the direction of the development of sorption naterials of wide functional purpose. All sorbents can be used in separation processes: due to their coarse dispersion and mechanical strength, they can be used as fillers for sorption columns.The direction of early works is the development of amorphous hydrophosphates and double hyd­rated oxides of multivalent metals, intended for the removal of toxic inorganic ions from water (arsenate-, chromate- and borate-anions, Cu2+, Pb2+, Cd2+cations etc.). Currently, attention is focused on the development of composite materials.The base of inorganic composites is hydrophosphate and oxide sorbents, and the modifiers are the advanced carbon materials, lithium-titanium and lithium-titanium-manganese spinels etc.Sorbents based on ion-exchange resins modified with inorganic ionites have also been developed.The combination of various components in composites makes it possible to obtain sorbents with improved properties (faster sorption, increased capacity and selectivity, sorption capacity in a wider pH range, easier regeneration) or multifunctional materials that sorb both inorganic and orga­nic compounds, for example, pesticides. Prospective field of research is the development of technologies that include not only the extraction of toxic and valuable components from liquids of natural, technological and biogenic origin, but also the regeneration of the sor­bent and processing of the concentrate to obtain commercial products.Thus, the integration of lithium sorption concentration into the process of reverse osmosis water desalination has been proposed. The processing of the solution formed during the regeneration of the sorbent includes the production of lithium carbonate and a complex fertilizer for acidic soils. Composites, the components of which are natural materials, are also in the focus of attention.Magnetic sorbents based on biopolymers, proposed for extraction of oil and oil products from water surfaces. Composites based on zeolites are used as containers for liquid fertilizers Another direction of research is the creation of composites - potential membrane modifiers for separation processes. V.I.Vernadsky Institute of General and Inorganic Chemistry 2023-01-27 Article Article Physical chemistry Физическая xимия Фізична xімія application/pdf https://ucj.org.ua/index.php/journal/article/view/506 10.33609/2708-129X.88.12.2022.139-174 Ukrainian Chemistry Journal; Vol. 88 No. 12 (2022): Ukrainian Chemistry Journal; 139-174 Украинский химический журнал; Том 88 № 12 (2022): Ukrainian Chemistry Journal; 139-174 Український хімічний журнал; Том 88 № 12 (2022): Український хімічний журнал; 139-174 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/506/258
institution Ukrainian Chemistry Journal
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datestamp_date 2023-03-22T13:10:11Z
collection OJS
language English
topic_facet sorbents
composites
hydrophosphates of multivalent metals
hydrated doubleoxides
ion exchangeresins
format Article
author Maltseva, Tetiana
Dzyazko, Yulliya
spellingShingle Maltseva, Tetiana
Dzyazko, Yulliya
DEVELOPMENT OF SORPTION MATERIALS OF WIDE FUNCTIONAL PURPOSE IN THE V.I. VERNADSKII INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY OF THE NAS OF UKRAINE
author_facet Maltseva, Tetiana
Dzyazko, Yulliya
author_sort Maltseva, Tetiana
title DEVELOPMENT OF SORPTION MATERIALS OF WIDE FUNCTIONAL PURPOSE IN THE V.I. VERNADSKII INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY OF THE NAS OF UKRAINE
title_short DEVELOPMENT OF SORPTION MATERIALS OF WIDE FUNCTIONAL PURPOSE IN THE V.I. VERNADSKII INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY OF THE NAS OF UKRAINE
title_full DEVELOPMENT OF SORPTION MATERIALS OF WIDE FUNCTIONAL PURPOSE IN THE V.I. VERNADSKII INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY OF THE NAS OF UKRAINE
title_fullStr DEVELOPMENT OF SORPTION MATERIALS OF WIDE FUNCTIONAL PURPOSE IN THE V.I. VERNADSKII INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY OF THE NAS OF UKRAINE
title_full_unstemmed DEVELOPMENT OF SORPTION MATERIALS OF WIDE FUNCTIONAL PURPOSE IN THE V.I. VERNADSKII INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY OF THE NAS OF UKRAINE
title_sort development of sorption materials of wide functional purpose in the v.i. vernadskii institute of general and inorganic chemistry of the nas of ukraine
description The review is devoted to the work, which were performed at the V.I. Vernadskii Institute of General and Inorganic Chemistry of the NAS of Ukraine according to the direction of the development of sorption naterials of wide functional purpose. All sorbents can be used in separation processes: due to their coarse dispersion and mechanical strength, they can be used as fillers for sorption columns.The direction of early works is the development of amorphous hydrophosphates and double hyd­rated oxides of multivalent metals, intended for the removal of toxic inorganic ions from water (arsenate-, chromate- and borate-anions, Cu2+, Pb2+, Cd2+cations etc.). Currently, attention is focused on the development of composite materials.The base of inorganic composites is hydrophosphate and oxide sorbents, and the modifiers are the advanced carbon materials, lithium-titanium and lithium-titanium-manganese spinels etc.Sorbents based on ion-exchange resins modified with inorganic ionites have also been developed.The combination of various components in composites makes it possible to obtain sorbents with improved properties (faster sorption, increased capacity and selectivity, sorption capacity in a wider pH range, easier regeneration) or multifunctional materials that sorb both inorganic and orga­nic compounds, for example, pesticides. Prospective field of research is the development of technologies that include not only the extraction of toxic and valuable components from liquids of natural, technological and biogenic origin, but also the regeneration of the sor­bent and processing of the concentrate to obtain commercial products.Thus, the integration of lithium sorption concentration into the process of reverse osmosis water desalination has been proposed. The processing of the solution formed during the regeneration of the sorbent includes the production of lithium carbonate and a complex fertilizer for acidic soils. Composites, the components of which are natural materials, are also in the focus of attention.Magnetic sorbents based on biopolymers, proposed for extraction of oil and oil products from water surfaces. Composites based on zeolites are used as containers for liquid fertilizers Another direction of research is the creation of composites - potential membrane modifiers for separation processes.
publisher V.I.Vernadsky Institute of General and Inorganic Chemistry
publishDate 2023
url https://ucj.org.ua/index.php/journal/article/view/506
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AT dzyazkoyulliya developmentofsorptionmaterialsofwidefunctionalpurposeinthevivernadskiiinstituteofgeneralandinorganicchemistryofthenasofukraine
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last_indexed 2025-09-24T17:43:48Z
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