SYNTHESIS AND ELECTRICAL CONDUCTIVITY OF SOLID SOLUTIONS OF THE SYSTEM RbF-PbF2-SnF2

• Date: 2019
• Author Affiliations: Yuliay Pogorenko — Vernadsky Institute of General and Inorganic Chemistry of National Academy of Sciences of Ukraine, 32-34 Aсademiс Palladin Avenue, Kyiv; Anatoliy Omel’chuk — Vernadsky Institute of General and Inorganic Chemistry of National Academy of Sciences of Ukraine, 32-34 Aсademiс Palladin Avenue, Kyiv; Roman Pshenichny — Sumy State University, 2 Rimsky-Korsakov Str., Sumy; Anton Nagornyi — National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prosp. Peremohy, Kyiv
• Keywords: keywords
• Main Authors: Pogorenko, Yuliay, Omel’chuk, Anatoliy, Pshenichny , Roman, Nagornyi, Anton
• Format: Article
• Language: English
• Published: V.I.Vernadsky Institute of General and Inorganic Chemistry 2019
• Subjects: solid fluoride conductive electrolytes; heterovalent substitution; non-stoichiometric fluorides; electrical conductivity
• Online Access: https://ucj.org.ua/index.php/journal/article/view/53
• Journal Title: Ukrainian Chemistry Journal

In the system RbF–PbF2–SnF2 are formed solid solutions of the heterovalent substitution RbxPb0,86‑xSn1,14F4-x (0 < x ≤ 0,2) with structure of β–PbSnF4. At x > 0,2 on the X-ray diffractograms, in addition to the basic structure...