ZIRCONIUM AND HAFNIUM DIHYDROXY­PHTHALO­CYANINATES: METHODS OF SYNTHESIS AND REACTIVITY

• Datum: 2023
• Автори та афіліації: Viktor Chernii — V. I. Vernadskii Institute of General and Inorganic Chemistry NAS of Ukraine, Kyiv, Ukraine; Iryna Tretyakova — IGIC; Natalia Fedosova — V. I. Vernadskii Institute of General and Inorganic Chemistry NAS of Ukraine, Kyiv, Ukraine; Iryna Denisenko — V. I. Vernadskii Institute of General and Inorganic Chemistry NAS of Ukraine, Kyiv, Ukraine; Yan Dovbii — V. I. Vernadskii Institute of General and Inorganic Chemistry NAS of Ukraine, Kyiv, Ukraine; Vladyslava Kovalska — Institute of Molecular Biology and Genetics NAS of Ukraine, Kyiv, Ukraine
• Ключові слова: keywords
• Hauptverfasser: Chernii, Viktor, Tretyakova, Iryna, Fedosova, Natalia, Denisenko, Iryna, Dovbii, Yan, Kovalska, Vladyslava
• Format: Artikel
• Sprache: Englisch
• Veröffentlicht: V.I.Vernadsky Institute of General and Inorganic Chemistry 2023
• Online Zugang: https://ucj.org.ua/index.php/journal/article/view/533
• Назва журналу: Ukrainian Chemistry Journal

Usually in order to obtain out-of-plane sub­stituted phthalocyanine complexes of zirconium and hafnium (PcML2), the reaction of substitution of chlorine atoms in dichloridophthalocyaninates PcMCl2 is used. How­ever, this method has some limitations because during this reaction, hydrogen chloride is...