LANTHANIDE-PORPHYRINS AND LANTHANIDE-PHTHALOCYANINES: DEVELOPMENT OF STABLE AND EFFECTIVE INFRARED 4F-EMITTIVE COMPOUNDS
This review is devoted to different synthetic approaches for obtaining lanthanide complexes with porphyrins and phthalocyanines, studying their structure and emission features. Lanthanide-tetrapyrroles can be core-coordinated or/and coordinated by additional binding sites in polytopic derivatives. I...
Saved in:
| Date: | 2023 |
|---|---|
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Published: |
V.I.Vernadsky Institute of General and Inorganic Chemistry
2023
|
| Online Access: | https://ucj.org.ua/index.php/journal/article/view/544 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Journal Title: | Ukrainian Chemistry Journal |
Institution
Ukrainian Chemistry Journal| id |
oai:ojs2.1444248.nisspano.web.hosting-test.net:article-544 |
|---|---|
| record_format |
ojs |
| spelling |
oai:ojs2.1444248.nisspano.web.hosting-test.net:article-5442023-07-11T08:16:56Z LANTHANIDE-PORPHYRINS AND LANTHANIDE-PHTHALOCYANINES: DEVELOPMENT OF STABLE AND EFFECTIVE INFRARED 4F-EMITTIVE COMPOUNDS Semenishyn, Nikolay Rusakova, Nataliia Smola, Serhii lanthanides; porphyrins; phthalocyanines; 4f-luminescence; sensitization. This review is devoted to different synthetic approaches for obtaining lanthanide complexes with porphyrins and phthalocyanines, studying their structure and emission features. Lanthanide-tetrapyrroles can be core-coordinated or/and coordinated by additional binding sites in polytopic derivatives. It is noteworthy that the polytopic tetrapyrroles allow obtaining polyheteronuclear compounds, which is quite interesting in terms of their particular 4f-sensitization mechanism. A general structural difference between core-coordinated lanthanide-porphyrins and lanthanide-phthalocyanines is the ability of the latter to easily form poly-decker compounds, which leads to interesting changes in photochemical processes including 4f-sensitization. The review also shows the main directions for the solution of the stability issue as well as different approaches for increasing the 4f-luminescence effectiveness. V.I.Vernadsky Institute of General and Inorganic Chemistry 2023-05-25 Article Article Inorganic Chemistry Неорганическая химия Неорганічна хімія application/pdf https://ucj.org.ua/index.php/journal/article/view/544 10.33609/2708-129X.89.04.2023.73-89 Ukrainian Chemistry Journal; Vol. 89 No. 4 (2023): Ukrainian Chemistry Journal; 73-89 Украинский химический журнал; Том 89 № 4 (2023): Ukrainian Chemistry Journal; 73-89 Український хімічний журнал; Том 89 № 4 (2023): Ukrainian Chemistry Journal; 73-89 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/544/276 |
| institution |
Ukrainian Chemistry Journal |
| baseUrl_str |
|
| datestamp_date |
2023-07-11T08:16:56Z |
| collection |
OJS |
| language |
English |
| topic_facet |
lanthanides porphyrins phthalocyanines 4f-luminescence sensitization. |
| format |
Article |
| author |
Semenishyn, Nikolay Rusakova, Nataliia Smola, Serhii |
| spellingShingle |
Semenishyn, Nikolay Rusakova, Nataliia Smola, Serhii LANTHANIDE-PORPHYRINS AND LANTHANIDE-PHTHALOCYANINES: DEVELOPMENT OF STABLE AND EFFECTIVE INFRARED 4F-EMITTIVE COMPOUNDS |
| author_facet |
Semenishyn, Nikolay Rusakova, Nataliia Smola, Serhii |
| author_sort |
Semenishyn, Nikolay |
| title |
LANTHANIDE-PORPHYRINS AND LANTHANIDE-PHTHALOCYANINES: DEVELOPMENT OF STABLE AND EFFECTIVE INFRARED 4F-EMITTIVE COMPOUNDS |
| title_short |
LANTHANIDE-PORPHYRINS AND LANTHANIDE-PHTHALOCYANINES: DEVELOPMENT OF STABLE AND EFFECTIVE INFRARED 4F-EMITTIVE COMPOUNDS |
| title_full |
LANTHANIDE-PORPHYRINS AND LANTHANIDE-PHTHALOCYANINES: DEVELOPMENT OF STABLE AND EFFECTIVE INFRARED 4F-EMITTIVE COMPOUNDS |
| title_fullStr |
LANTHANIDE-PORPHYRINS AND LANTHANIDE-PHTHALOCYANINES: DEVELOPMENT OF STABLE AND EFFECTIVE INFRARED 4F-EMITTIVE COMPOUNDS |
| title_full_unstemmed |
LANTHANIDE-PORPHYRINS AND LANTHANIDE-PHTHALOCYANINES: DEVELOPMENT OF STABLE AND EFFECTIVE INFRARED 4F-EMITTIVE COMPOUNDS |
| title_sort |
lanthanide-porphyrins and lanthanide-phthalocyanines: development of stable and effective infrared 4f-emittive compounds |
| description |
This review is devoted to different synthetic approaches for obtaining lanthanide complexes with porphyrins and phthalocyanines, studying their structure and emission features. Lanthanide-tetrapyrroles can be core-coordinated or/and coordinated by additional binding sites in polytopic derivatives. It is noteworthy that the polytopic tetrapyrroles allow obtaining polyheteronuclear compounds, which is quite interesting in terms of their particular 4f-sensitization mechanism. A general structural difference between core-coordinated lanthanide-porphyrins and lanthanide-phthalocyanines is the ability of the latter to easily form poly-decker compounds, which leads to interesting changes in photochemical processes including 4f-sensitization. The review also shows the main directions for the solution of the stability issue as well as different approaches for increasing the 4f-luminescence effectiveness. |
| publisher |
V.I.Vernadsky Institute of General and Inorganic Chemistry |
| publishDate |
2023 |
| url |
https://ucj.org.ua/index.php/journal/article/view/544 |
| work_keys_str_mv |
AT semenishynnikolay lanthanideporphyrinsandlanthanidephthalocyaninesdevelopmentofstableandeffectiveinfrared4femittivecompounds AT rusakovanataliia lanthanideporphyrinsandlanthanidephthalocyaninesdevelopmentofstableandeffectiveinfrared4femittivecompounds AT smolaserhii lanthanideporphyrinsandlanthanidephthalocyaninesdevelopmentofstableandeffectiveinfrared4femittivecompounds |
| first_indexed |
2025-09-24T17:43:50Z |
| last_indexed |
2025-09-24T17:43:50Z |
| _version_ |
1849658127253766144 |