CRYSTAL STRUCTURES AND SPECTROSCOPIC CHARACTERISTICS OF COMPLEXES OF LANTHANOIDES WITH AMINOCARBOXYPHOSPHONIC ACIDS (review)
The review is devoted to a new class of complexones – aminocarboxyphosphonic acids and lanthanide metal complexes based on them. Interest in such compounds is due to the specificity of the structure of aminocarboxyphosphonic acids molecules, which contain various functional acid groups (carboxylic...
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| Datum: | 2024 |
|---|---|
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| Format: | Artikel |
| Sprache: | English |
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V.I.Vernadsky Institute of General and Inorganic Chemistry
2024
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| Online Zugang: | https://ucj.org.ua/index.php/journal/article/view/642 |
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| Назва журналу: | Ukrainian Chemistry Journal |
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oai:ojs2.1444248.nisspano.web.hosting-test.net:article-6422025-01-28T08:23:33Z CRYSTAL STRUCTURES AND SPECTROSCOPIC CHARACTERISTICS OF COMPLEXES OF LANTHANOIDES WITH AMINOCARBOXYPHOSPHONIC ACIDS (review) Trunova, Olena complexes, aminocarboxyphosphonates, lanthanides, crystal structure, luminescence. The review is devoted to a new class of complexones – aminocarboxyphosphonic acids and lanthanide metal complexes based on them. Interest in such compounds is due to the specificity of the structure of aminocarboxyphosphonic acids molecules, which contain various functional acid groups (carboxylic and phosphonic) at one main nitrogen atom, which differ significantly in basicity, charge, stereochemistry and size. This provides a wide range of coordination possibilities of ligands, which most fully satisfy the spatial requirements of the complexing ion and allows obtaining polynuclear structures of an unusual structure in the crystalline state. The article summarizes the literature data obtained by various authors regarding the study of the structure and spectral properties of aminocarboxyphosphonates of 4-f metals in solutions and crystals, their thermal properties, structural features, prospects for creating multifunctional technical materials based on them are considered. V.I.Vernadsky Institute of General and Inorganic Chemistry 2024-03-29 Article Article Inorganic Chemistry Неорганическая химия Неорганічна хімія application/pdf https://ucj.org.ua/index.php/journal/article/view/642 10.33609/2708-129X.90.2.2024.41-66 Ukrainian Chemistry Journal; Vol 90 No 2 (2024): Ukrainian Chemistry Journal; 41-66 Украинский химический журнал; Том 90 № 2 (2024): Ukrainian Chemistry Journal; 41-66 Український хімічний журнал; Том 90 № 2 (2024): Ukrainian Chemistry Journal; 41-66 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/642/321 |
| institution |
Ukrainian Chemistry Journal |
| baseUrl_str |
|
| datestamp_date |
2025-01-28T08:23:33Z |
| collection |
OJS |
| language |
English |
| topic_facet |
complexes aminocarboxyphosphonates lanthanides crystal structure luminescence. |
| format |
Article |
| author |
Trunova, Olena |
| spellingShingle |
Trunova, Olena CRYSTAL STRUCTURES AND SPECTROSCOPIC CHARACTERISTICS OF COMPLEXES OF LANTHANOIDES WITH AMINOCARBOXYPHOSPHONIC ACIDS (review) |
| author_facet |
Trunova, Olena |
| author_sort |
Trunova, Olena |
| title |
CRYSTAL STRUCTURES AND SPECTROSCOPIC CHARACTERISTICS OF COMPLEXES OF LANTHANOIDES WITH AMINOCARBOXYPHOSPHONIC ACIDS (review) |
| title_short |
CRYSTAL STRUCTURES AND SPECTROSCOPIC CHARACTERISTICS OF COMPLEXES OF LANTHANOIDES WITH AMINOCARBOXYPHOSPHONIC ACIDS (review) |
| title_full |
CRYSTAL STRUCTURES AND SPECTROSCOPIC CHARACTERISTICS OF COMPLEXES OF LANTHANOIDES WITH AMINOCARBOXYPHOSPHONIC ACIDS (review) |
| title_fullStr |
CRYSTAL STRUCTURES AND SPECTROSCOPIC CHARACTERISTICS OF COMPLEXES OF LANTHANOIDES WITH AMINOCARBOXYPHOSPHONIC ACIDS (review) |
| title_full_unstemmed |
CRYSTAL STRUCTURES AND SPECTROSCOPIC CHARACTERISTICS OF COMPLEXES OF LANTHANOIDES WITH AMINOCARBOXYPHOSPHONIC ACIDS (review) |
| title_sort |
crystal structures and spectroscopic characteristics of complexes of lanthanoides with aminocarboxyphosphonic acids (review) |
| description |
The review is devoted to a new class of complexones – aminocarboxyphosphonic acids and lanthanide metal complexes based on them. Interest in such compounds is due to the specificity of the structure of aminocarboxyphosphonic acids molecules, which contain various functional acid groups (carboxylic and phosphonic) at one main nitrogen atom, which differ significantly in basicity, charge, stereochemistry and size. This provides a wide range of coordination possibilities of ligands, which most fully satisfy the spatial requirements of the complexing ion and allows obtaining polynuclear structures of an unusual structure in the crystalline state. The article summarizes the literature data obtained by various authors regarding the study of the structure and spectral properties of aminocarboxyphosphonates of 4-f metals in solutions and crystals, their thermal properties, structural features, prospects for creating multifunctional technical materials based on them are considered. |
| publisher |
V.I.Vernadsky Institute of General and Inorganic Chemistry |
| publishDate |
2024 |
| url |
https://ucj.org.ua/index.php/journal/article/view/642 |
| work_keys_str_mv |
AT trunovaolena crystalstructuresandspectroscopiccharacteristicsofcomplexesoflanthanoideswithaminocarboxyphosphonicacidsreview |
| first_indexed |
2025-09-24T17:43:55Z |
| last_indexed |
2025-09-24T17:43:55Z |
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1844168187680129024 |