STRUCTURE AND SPECTRAL EVALUATION OF COVALENCY IN ND(III) TETRAKIS COMPLEXES WITH CARBACYLAMIDOPHOSPHATE LIGANDS

• Дата: 2025
• Автори та афіліації: Mariia Struhatska — Faculty of Chemistry, Taras Shevchenko National University of Kyiv; Nataliia Kariaka — Faculty of Chemistry, Taras Shevchenko National University of Kyiv; Viktor Trush — Faculty of Chemistry, Taras Shevchenko National University of Kyiv; Viktoriya Dyakonenko — SSI “Institute for Single Crystals”, National Academy of Science of Ukraine; Svitlana Shishkina — SSI “Institute for Single Crystals”, National Academy of Science of Ukraine; Institute of Organic Chemistry of the National Academy of Sciences of Ukraine; Sergii Smola — A.V. Bogatsky Physicochemical Institute of the National Academy of Sciences of Ukraine; Nataliia Rusakova — A.V. Bogatsky Physicochemical Institute of the National Academy of Sciences of Ukraine; Volodymyr Amirkhanov — Faculty of Chemistry, Taras Shevchenko National University of Kyiv
• Ключові слова: keywords
• Автори: Struhatska, Mariia, Kariaka, Nataliia, Trush, Viktor, Dyakonenko, Viktoriya, Shishkina, Svitlana, Smola, Sergii, Rusakova, Nataliia, Amirkhanov, Volodymyr
• Формат: Стаття
• Мова: Англійська
• Опубліковано: V.I.Vernadsky Institute of General and Inorganic Chemistry 2025
• Онлайн доступ: https://ucj.org.ua/index.php/journal/article/view/755
• Назва журналу: Ukrainian Chemistry Journal

Two neodymium(III) tetrakis complexes with different carbacylamidophosphate ligands and a tetraethylammonium cation of the formulas NEt4[NdL14] (1Nd) and NEt4[NdL24]·iPrOH (2Nd) were synthesized, where [L1]⁻ is dimethyl-N-trichloroacetyl­ami­­dophosphate, Cl3CC(O)NP(O)(OCH3)2⁻, and [L2]⁻ is diphenyl...