ELECTROCHEMICAL SYNTHESIS OF FLUORINATED HETEROCYCLIC COMPOUNDS

Fluorine-containing heterocycles play a crucial role in the pharmaceutical, agrochemical, and materials industries. The pursuit of effective and sustainable synthesis methods has dri­ven the development of electrochemistry as a compelling alternative to conventional chemical transformations. Among t...

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Datum:2025
Hauptverfasser: Wzorek, Alicja, Ono, Taizo, Baecker, Daniel, Zhang, Wei, Soloshonok, Vadim
Format: Artikel
Sprache:Englisch
Veröffentlicht: V.I.Vernadsky Institute of General and Inorganic Chemistry 2025
Online Zugang:https://ucj.org.ua/index.php/journal/article/view/757
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Назва журналу:Ukrainian Chemistry Journal

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Ukrainian Chemistry Journal
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author Wzorek, Alicja
Ono, Taizo
Baecker, Daniel
Zhang, Wei
Soloshonok, Vadim
author_facet Wzorek, Alicja
Ono, Taizo
Baecker, Daniel
Zhang, Wei
Soloshonok, Vadim
author_sort Wzorek, Alicja
baseUrl_str
collection OJS
datestamp_date 2026-03-09T13:19:17Z
description Fluorine-containing heterocycles play a crucial role in the pharmaceutical, agrochemical, and materials industries. The pursuit of effective and sustainable synthesis methods has dri­ven the development of electrochemistry as a compelling alternative to conventional chemical transformations. Among these approaches, electrochemistry has emerged as a particularly promising technique for orchestrating multibond-forming processes under mild, environmentally benign conditions. This review highlights key advances over the past decade in the electrochemical synthesis of fluorinated heterocyclic compounds, encompassing bimolecular, trimolecular, and tetramolecular reactions. Emphasis is placed on multicomponent cascade strategies, radical-mediated couplings, and oxidant-free cyclizations that afford broad functional group tolerance and fluorine incorporation flexibility. Collectively, this work serves as a resource for researchers developing next-generation sustainable synthetic platforms tailored to fluorinated heterocycles with diverse structural and biological profiles.
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spelling oai:ojs2.1444248.nisspano.web.hosting-test.net:article-7572026-03-09T13:19:17Z ELECTROCHEMICAL SYNTHESIS OF FLUORINATED HETEROCYCLIC COMPOUNDS Wzorek, Alicja Ono, Taizo Baecker, Daniel Zhang, Wei Soloshonok, Vadim Electrochemistry, Heterocyclic Compounds, Fluorine, Fluorinated Pharmaceuticals, Green Chemistry, Sustainable Synthesis. Fluorine-containing heterocycles play a crucial role in the pharmaceutical, agrochemical, and materials industries. The pursuit of effective and sustainable synthesis methods has dri­ven the development of electrochemistry as a compelling alternative to conventional chemical transformations. Among these approaches, electrochemistry has emerged as a particularly promising technique for orchestrating multibond-forming processes under mild, environmentally benign conditions. This review highlights key advances over the past decade in the electrochemical synthesis of fluorinated heterocyclic compounds, encompassing bimolecular, trimolecular, and tetramolecular reactions. Emphasis is placed on multicomponent cascade strategies, radical-mediated couplings, and oxidant-free cyclizations that afford broad functional group tolerance and fluorine incorporation flexibility. Collectively, this work serves as a resource for researchers developing next-generation sustainable synthetic platforms tailored to fluorinated heterocycles with diverse structural and biological profiles. V.I.Vernadsky Institute of General and Inorganic Chemistry 2025-12-25 Article Article Physical chemistry Физическая xимия Фізична xімія application/pdf https://ucj.org.ua/index.php/journal/article/view/757 10.33609/2708-129X.91.11.2025.35-62 Ukrainian Chemistry Journal; Vol. 91 No. 11 (2025): Ukrainian Chemistry Journal; 35-62 Украинский химический журнал; Том 91 № 11 (2025): Ukrainian Chemistry Journal; 35-62 Український хімічний журнал; Том 91 № 11 (2025): Ukrainian Chemistry Journal; 35-62 2708-129X 2708-1281 en https://ucj.org.ua/index.php/journal/article/view/757/392
spellingShingle Wzorek, Alicja
Ono, Taizo
Baecker, Daniel
Zhang, Wei
Soloshonok, Vadim
ELECTROCHEMICAL SYNTHESIS OF FLUORINATED HETEROCYCLIC COMPOUNDS
title ELECTROCHEMICAL SYNTHESIS OF FLUORINATED HETEROCYCLIC COMPOUNDS
title_full ELECTROCHEMICAL SYNTHESIS OF FLUORINATED HETEROCYCLIC COMPOUNDS
title_fullStr ELECTROCHEMICAL SYNTHESIS OF FLUORINATED HETEROCYCLIC COMPOUNDS
title_full_unstemmed ELECTROCHEMICAL SYNTHESIS OF FLUORINATED HETEROCYCLIC COMPOUNDS
title_short ELECTROCHEMICAL SYNTHESIS OF FLUORINATED HETEROCYCLIC COMPOUNDS
title_sort electrochemical synthesis of fluorinated heterocyclic compounds
topic_facet Electrochemistry
Heterocyclic Compounds
Fluorine
Fluorinated Pharmaceuticals
Green Chemistry
Sustainable Synthesis.
url https://ucj.org.ua/index.php/journal/article/view/757
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AT onotaizo electrochemicalsynthesisoffluorinatedheterocycliccompounds
AT baeckerdaniel electrochemicalsynthesisoffluorinatedheterocycliccompounds
AT zhangwei electrochemicalsynthesisoffluorinatedheterocycliccompounds
AT soloshonokvadim electrochemicalsynthesisoffluorinatedheterocycliccompounds