THE STUDY OF LIGAND EXCHANGE REACTIONS IN THE MIXED-LIGAND HAFNIUM PHTHALO-CYANINE COMPLEX BY 1H NMR SPECTROSCOPY

• Datum: 2026
• Hauptverfasser: Tretyakova, Iryna, Fedosova, Natalia, Dovbiy, Yan, Chernii, Viktor
• Format: Artikel
• Sprache: Englisch
• Veröffentlicht: V.I.Vernadsky Institute of General and Inorganic Chemistry 2026
• Online Zugang: https://ucj.org.ua/index.php/journal/article/view/771
• Назва журналу: Ukrainian Chemistry Journal

The reactivity of a mixed-ligand alkylamino-β-ketoenolato decanoatophthalocyaninate of hafnium was investigated by 1H NMR spectroscopy via substitution of axial ligands in reactions with para-isopropoxybenzoic acid and dibenzoylmethane. The initial complex PcHf(C₉H₁₉COO)L was shown to exhibit high r...