ПОЛІЕДРИЧНІ ФОРМИ МОНОКРИСТАЛІВ АЛМАЗУ З РОЗВИНУТИМИ ГРАНЯМИ ТЕТРАГОНТРИОКТАЕДРА
The growth process of diamond single crystals in the region of thermodynamic stability at high pressures of 6-6.5 GPa and temperatures of 1300-1500 oC (HPNT crystallization) by means of solution-melt crystallization on seeds was investigated. It was shown that when Fe-Co-Ti-Cu solvents are used, pol...
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| Date: | 2023 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | Ukrainian |
| Published: |
Институт сверхтвердых материалов им. В. Н. Бакуля Национальной академии наук Украины
2023
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| Subjects: | |
| Online Access: | http://altis-ism.org.ua/index.php/ALTIS/article/view/300 |
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| Journal Title: | Tooling materials science |
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Tooling materials science| Summary: | The growth process of diamond single crystals in the region of thermodynamic stability at high pressures of 6-6.5 GPa and temperatures of 1300-1500 oC (HPNT crystallization) by means of solution-melt crystallization on seeds was investigated. It was shown that when Fe-Co-Ti-Cu solvents are used, polyhedral forms with the development of {311} faces up to 50-57% of the total surface area of the crystal are formed. The peculiarities of crystallization of diamonds of tetragontrioctahedral habit were studied using the high-pressure equipment TS40, structurally perfect crystals weighing 1.97 - 3.75 carats were obtained in growing cycles lasting 96 - 168 hours. Photogrammetry was used to study the features of crystal formation and surface growth accessories depending on the growing conditions, and the prospect of using the results to create diamond semiconductors when doping {311} growth sectors with electrically active impurities was considered.
Key words: diamond, single crystal, impurity, habitus, photogrammetry, crystal faces. |
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