Перетворення заміщених 3-гідрокси-4-[(2Е)-3-арилпроп-2-еноїл]-1,5-дигідро-2Н-пірол-2-онів під дією I2/ДМСО у похідні 2-арил-5,6-дигідропірано[2,3-с]пірол-4,7-діонів

The effective and simple synthetic preparative procedure for obtaining of various derivatives of 2-aryl-5,6-dihydropyrano[2,3-c]pyrrole-4,7-diones applying the I2/DMSO oxidation of 3-hydroxy-4-[(2E)-3-arylprop-2-enoyl]-1,5-dihydro-2H-pyrrol-2-ones was developed. This protocol was found to be compati...

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Bibliographic Details
Date:2021
Main Authors: Vydzhak, Roman N., Panchishin, Svitlana Ya., Prostota, Yaroslav O., Brovarets, Volodymyr S.
Format: Article
Language:English
Published: V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine 2021
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Online Access:https://bioorganica.com.ua/index.php/journal/article/view/20
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Journal Title:Ukrainica Bioorganica Acta

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Ukrainica Bioorganica Acta
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Summary:The effective and simple synthetic preparative procedure for obtaining of various derivatives of 2-aryl-5,6-dihydropyrano[2,3-c]pyrrole-4,7-diones applying the I2/DMSO oxidation of 3-hydroxy-4-[(2E)-3-arylprop-2-enoyl]-1,5-dihydro-2H-pyrrol-2-ones was developed. This protocol was found to be compatible with a wide range of substituents and gave the reliable synthetic pathway for the obtaining of target compounds with a wide range of substituents under mild conditions. All obtained substances can be easily isolated and purified by crystallization without application of more complex and labour intensive purification methods