Особливості застосування хром-цирконієвих бронз та способи покращення їх властивостей

Physico-Technological Institute of Metals and Alloys of the NAS of Ukraine (Kyiv, Ukraine) Received 14.02.2022 UDK 669.35:669.017.13 Modern development of mechanical engineering and electrical engineering requires alloys that have high electrical conductivity and sufficient strength parameters under...

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Datum:2023
Hauptverfasser: Ліхацький, Р. Ф., Ворон, М. М., Нарівський, А. В.
Format: Artikel
Sprache:Ukrainian
Veröffentlicht: National Academy of Sciences of Ukraine, Physical-Technological Institute of Metals and Alloys of NAS of Ukraine 2023
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Online Zugang:https://plit-periodical.org.ua/index.php/plit/article/view/features-chromium-zirconium-bronzes-application-and-ways-improve
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Zusammenfassung:Physico-Technological Institute of Metals and Alloys of the NAS of Ukraine (Kyiv, Ukraine) Received 14.02.2022 UDK 669.35:669.017.13 Modern development of mechanical engineering and electrical engineering requires alloys that have high electrical conductivity and sufficient strength parameters under normal conditions and at elevated temperatures, due to the peculiarities of application. The production of such materials and products from them should be simple and cheap, due to the large volumes of their consumption. The mechanical properties of pure and low-alloyed copper are mediocre, but by alloying it with chromium and zirconium, it is possible to greatly increase the strength, while maintaining the electrical conductivity of more than 80 % of the electrical conductivity of pure copper. Heat treatment of bronze leads to the release of dispersed particles with low solubility in the matrix metal at elevated temperatures, followed by dispersion hardening. This is what ensures the high electrical conductivity of such bronzes. It is shown that the use as alloying elements of most other metals is economically less feasible or leads to a significant loss of electrical conductivity. The paper considers an influence of different types of alloys hardening of Cu-Cr and Cu-Cr-Zr systems on electrical conductivity, their mechanical and operational properties. Studies characterize the influence on the alloys characteristics such parameters as different types of deformation, thermomechanical and heat treatment. The properties of Cu-Cr-Zr bronze, including in various technological states, as one of the most common alloys of this system are indicated. Based on the analysis of information, it is concluded that an additional increase in the application properties of this alloys type is possible by microalloying with insoluble components - V, Mo, W, Nb, Hf.   References 1 Shangina D. V. (2010). Structure and properties of ultrafine-grained Cu–Cr alloys after shear under pressure. Collection of materials of the VII Russian annual conference of young researchers and graduate students "Physical Chemistry and Technology of Inorganic Materials". Moscow: RAS, pp. 78–80. [In Russian].2 Osintsev O. E., Fedorov V. N. (2004). Copper and copper alloys. Moscow: Mashinostroenie, 336 p. [In Russian].3 Nikolaev A. K., Kostin S. A. (2012). Copper and heat-resistant copper alloys: [encyclopedia.terminologist. words: a fundamental reference book]. Moscow: DPK Press, 715 p. [In Russian].4 Kolachev B. A., Elagin V. N., Livanov V. A. (2001). Metal science and heat treatment of non- ferrous metals and alloys. Moscow: MISIS, 416 p. [In Russian].5 Straffelini G. (2005). Dry sliding wear of Cu-Be alloys. Wear. No. 6, pp. 506–5116 Lerner J., McMahon Jr C. J. (2002). The effect of precipitation hardening on the Hg-induced embrittlement of a Cu–Be alloy. Mater. Sci. Eng. A. Vol. 336. No. 1-2, pp.72–74.7 Tian W. (2018). Effect of Zr on as-cast microstructure and properties of Cu-Cr alloy. Vacuum. No. 149, pp. 238–247.8 Revina N. I. et al. (1978). Investigation of the properties of low-alloy alloys of the copper- chromium-zirconium system. No. 6, pp. 108–110. [In Russian].9 Khomskaya I. V. et al. (2013). Investigation of the structure, physical and mechanical properties and thermal stability of nanostructured copper and bronze obtained by DCAP. Letters about materials. Vol. 3, pp.150–154. [In Russian].10 Melekhin N. V., Chuvildeev V. N. (2011). Influence of equal-channel–angular pressing on the process of particles precipitation in Cu–Cr–Zr alloy. Solid state physics. Bulletin of the Nizhny Novgorod University Lobachevsky. No. 5, pp. 55–61. [In Russian].11 Shangina D. V. (2011). Structure and properties of nano- and submicrocrystalline Cu–Cr copper alloys with a chromium content of 0.75–27%. Abstracts of the conference "66th Days of Science of MISIS students". Moscow: MISIS, P. 43. [In Russian].12 Shangina D. V. (2011). Influence of alloying with hafnium on the thermal stability of chromium bronze after severe plastic deformation. Collection of materials of the VIII Russian annual conference of young researchers and graduate students "Physical Chemistry and Technology of Inorganic Materials". Moscow: RAS, pp. 678–880. [In Russian].13 Stobrawa J., Ciura L., Rdzawski Z. (1996). Rapidly solidified strips of Cu-Cr alloys. Scr. Mater. Vol. 34. No. 11, pp. 1759–1763.14 Zhilyaev A. P. (2013). Wear resistance and electroconductivity in copper processed by severe plastic deformation. Wear. Vol. 305. No. 1-2, pp. 89–99.15 Rozenberg V. M., Dzutsev V. T. (1989). Diagrams of isothermal decomposition in copper- based alloys: [handbook]. Moscow: Metallurgy, 326 p. [In Russian].16 Nikolaev A. K., Novikov A. I., Rozenberg V. M. (1983). Chrome bronzes. Moscow: Metallurgy, 175 p. [In Russian].17 Wei K. X. (2011). Microstructure, mechanical properties and electrical conductivity of industrial Cu-0.5%Cr alloy processed by severe plastic deformation. Mater. Sci. Eng. A. Vol. 528. No. 3, pp. 1478–1484.18 Wang N. (2006). The thermodynamic re-assessment of the Cu-Zr system. Calphad Comput. Coupling Phase Diagrams Thermochem. Vol. 30. No. 4, pp. 461–469.19 Mishnev R. (2015). Deformation microstructures, strengthening mechanisms, and electrical conductivity in a Cu-Cr-Zr alloy. Mater. Sci. Eng. A. Vol. 629, pp. 29–40.20 Kato M. (2014). Hall-Petch Relationship and Dislocation Model for Deformation of UltrafineGrained and Nanocrystalline Metals. Mater. Trans. Vol. 55. No. 1, pp. 19–24.21 Malopheyev S., Kulitskiy V., Kaibyshev R. (2017). Deformation structures and strengthening mechanisms in an Al-Mg-Sc-Zr alloy. J. Alloys Compd. Vol. 698, pp. 957–966.22 Hansen N. (2005). Boundary strengthening in undeformed and deformed polycrystals. Mater. Sci. Eng. A. Vol. 409. No. 1-2, pp. 39–45.23 Hansen N. (2004). Hall-petch relation and boundary strengthening. Scr. Mater. Vol. 51. No. 8, pp. 801–806.24 Beladi H., Cizek P., Hodgson P. D. (2010). On the characteristics of substructure development through dynami recrystallization. Acta Mater. A. Vol. 58. No. 9, pp. 3531–3541.25 Purcek G. (2018). Influence of high-pressure torsion-induced grain refinement and subsequent aging on tribological properties of Cu-Cr-Zr alloy. J. Alloys Compd. Vol. 742, pp. 325–333.26 Mu S. G. (2008). Study on microstructure and properties of aged Cu-Cr-Zr-Mg-RE alloy. Mater. Sci. Eng. A. Vol. 475. No. 1-2, pp. 235–240.27 Semenov V. I. (2015). Tribological properties of technically pure copper with different microstructure in contact with graphite-containing material. Friction and wear. Vol. 36. No. 2, pp. 154–160. [In Russian].