Якісний аналіз кластеризації в спиртово-водних розчинах
The specific features of clustering in the aqueous solutions of monohydric alcohols with concentrations higher than that at the peculiar point are discussed. Clustering is a result of the formation of hydrogen bonds between water and alcohol molecules, the energy of which some-what exceeds the energ...
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| Datum: | 2018 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | English Ukrainian |
| Veröffentlicht: |
Publishing house "Academperiodika"
2018
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| Schlagworte: | |
| Online Zugang: | https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2018054 |
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| Назва журналу: | Ukrainian Journal of Physics |
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Ukrainian Journal of Physics| Zusammenfassung: | The specific features of clustering in the aqueous solutions of monohydric alcohols with concentrations higher than that at the peculiar point are discussed. Clustering is a result of the formation of hydrogen bonds between water and alcohol molecules, the energy of which some-what exceeds the energy of hydrogen bonds in the water-water and alcohol-alcohol molecular pairs. Elementary clusters are assumed to be formed, whose composition is fixed at the solution concentrations lower than that at the peculiar point and changes according to a certain law at higher concentrations. The solution clustering degree was determined as a function of the solution concentration and the temperature. |
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