Динамiка iон-фосфатної ґратки ДНК в лiвiй формi подвiйної спiралi
The conformational vibrations of Z-DNA with counterions are studied in the framework of a phenomenological model developed. The structure of a left-handed double helix with counterions neutralizing the negatively charged phosphate groups of DNA is considered as an ion-phosphate lattice. The frequenc...
Збережено в:
| Дата: | 2018 |
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| Автори: | , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Publishing house "Academperiodika"
2018
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| Теми: | |
| Онлайн доступ: | https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2018325 |
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| Назва журналу: | Ukrainian Journal of Physics |
Репозитарії
Ukrainian Journal of Physics| Резюме: | The conformational vibrations of Z-DNA with counterions are studied in the framework of a phenomenological model developed. The structure of a left-handed double helix with counterions neutralizing the negatively charged phosphate groups of DNA is considered as an ion-phosphate lattice. The frequencies and the Raman intensities for the modes of Z-DNA with Na+ and Mg2+ ions are calculated, and the low-frequency Raman spectra are built. At the spectral interval about the frequency 150 cm^-1; a new mode of ion-phosphate vibrations, which characterizes the vibrations of Mg2+ counterions, is found. The results of our calculations show that the intensities of Z-DNA modes are sensitive to the concentration of magnesium counterions. The obtained results describe well the experimental Raman spectra of Z-DNA. |
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