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Вплив передростового відпалу вихідного матеріалу на властивості неочищених монокристалів телуриду кадмію, отриманих методом сублімації

The effect of high-temperature annealing of a nominally undoped CdTe charge under dynamic vacuum conditions on the electrical and optical properties of single crystals grown from this charge with the use of a modified physical vapor transport method has been examined. It is shown that the annealing...

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Bibliographic Details
Main Authors: Popovych, V.D., Gnatenko, Yu.P., Bukivskij, P.M., Potera, P.
Format: Article
Language:Ukrainian
English
Published: Publishing house "Academperiodika" 2012
Subjects:
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Online Access:https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2021205
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Summary:The effect of high-temperature annealing of a nominally undoped CdTe charge under dynamic vacuum conditions on the electrical and optical properties of single crystals grown from this charge with the use of a modified physical vapor transport method has been examined. It is shown that the annealing results in the disappearance or an extinction of chlorine-related lines in the low-temperature photoluminescence spectra and the absorption bands in the long-wavelength absorption-edge spectra of the crystals concerned, as well as in a drastic fall of their resistivity. The observed alterations are explained by a removal of the Cl impurity during the annealing owing to a high volatility of chlorine compounds.