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Функціональний розклад вільної енергії як узагальнений підхід до рівняння стану густих флюїдів
A version of the thermodynamic perturbation theory based on a scaling transformation of the partition function has been applied to the statistical derivation of the equation of state in a high-pressure region. Two modifications of the equations of state have been obtained on the basis of the free en...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Publishing house "Academperiodika"
2012
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| Subjects: | |
| Online Access: | https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2021242 |
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| Summary: | A version of the thermodynamic perturbation theory based on a scaling transformation of the partition function has been applied to the statistical derivation of the equation of state in a high-pressure region. Two modifications of the equations of state have been obtained on the basis of the free energy functional perturbation series. The comparative analysis of the experimental PVT-data on the isothermal compression for the supercritical fluids of inert gases has been carried out. |
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