Особливості генерування енергетичних станів у напівпровіднику Lu1 – xVxNiSb

A comprehensive study of the crystal and electronic structures, thermodynamic, kinetic, energy, and magnetic properties of the Lu1−xVxNiSb semiconductor (x = 0÷0.10) has revealed the possibility for impurity V atoms to simultaneously occupy different crystallographic positions. At the same time, def...

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Datum:2023
Hauptverfasser: Romaka, V.V., Romaka, V.A., Stadnyk, Yu.V., Romaka, L.P., Plevachuk, Y.O., Horyn, A.M., Pashkevych, V.Z., Haraniuk, P.I.
Format: Artikel
Sprache:English
Veröffentlicht: Publishing house "Academperiodika" 2023
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Online Zugang:https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2023006
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Назва журналу:Ukrainian Journal of Physics

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Ukrainian Journal of Physics
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Zusammenfassung:A comprehensive study of the crystal and electronic structures, thermodynamic, kinetic, energy, and magnetic properties of the Lu1−xVxNiSb semiconductor (x = 0÷0.10) has revealed the possibility for impurity V atoms to simultaneously occupy different crystallographic positions. At the same time, defects of the acceptor or donor nature are generated in the crystal structure of the Lu1−xVxNiSb solid solution, and the corresponding energy states appear in the band gap ϵg. The concentration ratio of donor-acceptor states determines the position of the Fermi level ϵF and the mechanisms of electrical conductivity of Lu1−xVxNiSb. The results of the modeling of thermodynamic and transport properties of the semiconductor are consistent with experimental data. Understanding the mechanism of energy state generation in the semiconductor Lu1−xVxNiSb allows the modeling and production of new thermoelectric materials with a high efficiency of converting the thermal energy into the electrical one.