Структурна еволюція метастабільного поліморфу пара-крезолу
Time-dependent polymorphic transformations of para-cresol, a compound known for its multiple crystalline forms and diverse applications, were investigated. The behavior of the metastable form III of para-cresol, which is obtained as a result of relaxation of the metastable form II, was examined usin...
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| Date: | 2026 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English Ukrainian |
| Published: |
Publishing house "Academperiodika"
2026
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| Subjects: | |
| Online Access: | https://ujp.bitp.kiev.ua/index.php/ujp/article/view/2023925 |
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| Journal Title: | Ukrainian Journal of Physics |
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Ukrainian Journal of Physics| Summary: | Time-dependent polymorphic transformations of para-cresol, a compound known for its multiple crystalline forms and diverse applications, were investigated. The behavior of the metastable form III of para-cresol, which is obtained as a result of relaxation of the metastable form II, was examined using differential scanning calorimetry. Thermal analysis showed that the transformation of the metastable form III of para-cresol is slow, heterogeneous, and probabilistic in nature. The multi-peak decomposition of the melting curves indicates the coexistence of three polymorphs in the samples for a relatively long time. These results demonstrate that metastable forms of para-cresol can persist far longer than would normally be expected for thermodynamically unfavorable phases. |
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| DOI: | 10.15407/ujpe71.4.344 |