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Low temperature mixed spin state of Co³⁺ in LaCoO₃ evidenced from Jahn–Teller lattice distortions

Low temperature mixed spin state of Co³⁺ in LaCoO₃ evidenced from Jahn–Teller lattice distortions

One- and multi-phonon excitations of the single crystalline LaCoO₃ were studied using Raman spectroscopy in the temperature region of 5–300 K. First-order Raman spectra show a larger number of phonon modes than allowed for the rhombohedral structure. Additional phonon modes are interpreted in ter...

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Bibliographic Details
Main Authors: Gnezdilov, V., Choi, K.-Y., Pashkevich, Yu., Lemmens, P., Shiryaev, S., Bychkov, G., Barilo, S., Fomin, V., Yeremenko, A.V.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2006
Series:Физика низких температур
Subjects:
Динамика кристаллической решетки
Online Access:http://dspace.nbuv.gov.ua/handle/123456789/120131
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http://dspace.nbuv.gov.ua/handle/123456789/120131

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