Model description of the H–bonded transuranium complexes

• Дата: 1999
• Автори: Stasyuk, I.V., Ivankiv, O.L., Velychko, O.V., Holubets, T.V.
• Мова: English
• Опубліковано: Інститут фізики конденсованих систем НАН України 1999
• Назва видання: Condensed Matter Physics
• Онлайн доступ: http://dspace.nbuv.gov.ua/handle/123456789/120396
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Цитувати: Model description of the H–bonded transuranium complexes / I.V. Stasyuk, O.L. Ivankiv, O.V. Velychko, T.V. Holubets // Condensed Matter Physics. — 1999. — Т. 2, № 2(18). — С. 345-350. — Бібліогр.: 6 назв. — англ.

In the framework of configurational model it is established that regions of existence of various forms of actinide hydroxocomplexes at variation of solution pH depend on differences of configuration energies and temperature. Saturation effect is found out, which leads to a sharp change of ligand con...