Model description of the H–bonded transuranium complexes
In the framework of configurational model it is established that regions of existence of various forms of actinide hydroxocomplexes at variation of solution pH depend on differences of configuration energies and temperature. Saturation effect is found out, which leads to a sharp change of ligand con...
Збережено в:
| Дата: | 1999 |
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| Автори: | , , , |
| Мова: | English |
| Опубліковано: |
Інститут фізики конденсованих систем НАН України
1999
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| Назва видання: | Condensed Matter Physics |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/120396 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Model description of the H–bonded transuranium complexes / I.V. Stasyuk, O.L. Ivankiv, O.V. Velychko, T.V. Holubets // Condensed Matter Physics. — 1999. — Т. 2, № 2(18). — С. 345-350. — Бібліогр.: 6 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| Резюме: | In the framework of configurational model it is established that regions of
existence of various forms of actinide hydroxocomplexes at variation of solution pH depend on differences of configuration energies and temperature.
Saturation effect is found out, which leads to a sharp change of ligand concentration. Model of the polymerization of ionic groups UO₂[(OH)₂UO₂]²⁺ n into chain structure via hydrogen bonds is proposed. The thermodynamic
stability of such a formation is investigated depending on the number of
links at different temperatures and at various boundary conditions. |
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