Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and...
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| Дата: | 2002 |
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| Автори: | , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Інститут хімії поверхні ім. О.О. Чуйка НАН України
2002
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| Назва видання: | Поверхность |
| Теми: | |
| Онлайн доступ: | http://dspace.nbuv.gov.ua/handle/123456789/126358 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
irk-123456789-126358 |
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dspace |
| spelling |
irk-123456789-1263582017-11-21T03:02:49Z Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene Ignatovych, M. Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. Surface chemistry of silica and related sorbents The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and paramagnetic species formation, namely reduced molybdenum species (Mo⁵⁺ species) and radicals of benzene. Computer treatment of ESR experimental data revealed that there are several types of Mo⁵⁺ species and benzene radicals, the assignment of which is proposed. 2002 Article Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ. XXXX-0106 http://dspace.nbuv.gov.ua/handle/123456789/126358 en Поверхность Інститут хімії поверхні ім. О.О. Чуйка НАН України |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| language |
English |
| topic |
Surface chemistry of silica and related sorbents Surface chemistry of silica and related sorbents |
| spellingShingle |
Surface chemistry of silica and related sorbents Surface chemistry of silica and related sorbents Ignatovych, M. Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene Поверхность |
| description |
The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and paramagnetic species formation, namely reduced molybdenum species (Mo⁵⁺ species) and radicals of benzene. Computer treatment of ESR experimental data revealed that there are several types of Mo⁵⁺ species and benzene radicals, the assignment of which is proposed. |
| format |
Article |
| author |
Ignatovych, M. Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. |
| author_facet |
Ignatovych, M. Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. |
| author_sort |
Ignatovych, M. |
| title |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_short |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_full |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_fullStr |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_full_unstemmed |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_sort |
electron spin resonance study on mo-sio₂ and mo-tio₂ with adsorbed benzene |
| publisher |
Інститут хімії поверхні ім. О.О. Чуйка НАН України |
| publishDate |
2002 |
| topic_facet |
Surface chemistry of silica and related sorbents |
| url |
http://dspace.nbuv.gov.ua/handle/123456789/126358 |
| citation_txt |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ. |
| series |
Поверхность |
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AT ignatovychm electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene AT teslenkov electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene AT eremenkoa electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene AT ogenkov electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene AT chuikoa electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene |
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2023-10-18T20:50:38Z |
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2023-10-18T20:50:38Z |
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