Prediction of Stable Composition for High-Entropy Refractory Alloys

The common approach for evaluation of stability of multicomponent substitutional solid solutions using thermodynamic, mechanical, and topological parameters of the constituent elements is developed. The high-temperature systems based on refractory elements (W, Ta, Mo, Nb, V, Ti, Zr, Hf, Cr) are inve...

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Bibliographic Details
Date:2016
Main Authors: Melnick, A.B., Soolshenko, V.K.
Format: Article
Language:English
Published: Інститут металофізики ім. Г.В. Курдюмова НАН України 2016
Series:Металлофизика и новейшие технологии
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/112622
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Prediction of Stable Composition for High-Entropy Refractory Alloys / A.B. Melnick, V.K. Soolshenko // Металлофизика и новейшие технологии. — 2016. — Т. 38, № 10. — С. 1395-1405. — Бібліогр.: 25 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Summary:The common approach for evaluation of stability of multicomponent substitutional solid solutions using thermodynamic, mechanical, and topological parameters of the constituent elements is developed. The high-temperature systems based on refractory elements (W, Ta, Mo, Nb, V, Ti, Zr, Hf, Cr) are investigated using this approach. Optimal compositions for high-entropy alloys are obtained, and influence of various factors in the formation of stable alloys is described. As shown, the most resistant alloys have non-equiatomic element-contents’ ratios. The agreement between element distribution in experimental alloys and predicted stable compositions are obtained for the W— Ta—Mo—Nb and W—Ta—Mo—Nb—V systems.