Infrared studies of ortho-para conversion at Cl-atom and H-atom impurity centers in cryogenic solid hydrogen

• Datum: 2010
• Hauptverfasser: Raston, P.L., Kettwich, S.C., Anderson, D.T.
• Format: Artikel
• Sprache: English
• Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2010
• Schriftenreihe: Физика низких температур
• Schlagworte: Nanostructures and Impurity Centers in Cryogenic Environment
• Online Zugang: https://nasplib.isofts.kiev.ua/handle/123456789/117038
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Zitieren: Infrared studies of ortho-para conversion at Cl-atom and H-atom impurity centers in cryogenic solid hydrogen / P.L. Raston, S.C. Kettwich, D.T. Anderson // Физика низких температур. — 2010. — Т. 36, № 5. — С. 495-503. — Бібліогр.: 31 назв. — англ.

We report infrared spectroscopic studies of H₂ ortho-para (o/p) conversion in solid hydrogen doped with Clatoms at 2 K while the Cl+H₂(v=1)→HCl+H infrared-induced chemical reaction is occurring. The Cl-atom doped hydrogen crystals are synthesized using 355 nm in situ photodissociation of Cl₂ precurs...