Statistical model analysis of local structure of quaternary sphalerite crystals
At the 2004 Ural International Winter School, we introduced the statistical strained tetrahedron
 model and discussed ternary tetrahedron structured crystals. The model allows one to interpret
 x-ray absorption fine structure (EXAFS) data and extract quantitative information on ion s...
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| Опубліковано в: : | Физика низких температур |
|---|---|
| Дата: | 2007 |
| Автори: | , , , , , , , , , , , , |
| Формат: | Стаття |
| Мова: | Англійська |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2007
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/127732 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Statistical model analysis of local structure of quaternary
 sphalerite crystals / B.V. Robouch, A. Kisiel, A. Marcelli, E.M. Sheregii, M. Cestelli Guidi, M. Piccinini, J. Polit, J. Cebulski, A. Mycielski, V.I. Ivanov-Omskii, E. Sciesinska, J. Sciesinski, and E. Burattini // Физика низких температур. — 2007. — Т. 33, № 2-3. — С. 291-303. — Бібліогр.: 40 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862719461011750912 |
|---|---|
| author | Robouch, B.V. Kisie, A. Marcelli, A. Sheregii, E.M. Cestelli Guidi, M. Piccinini, M. Polit, J. Cebulski, J. Mycielsk, A. Ivanov-Omski, V.I. Sciesinska, E. Sciesinski, J. Burattini, E. |
| author_facet | Robouch, B.V. Kisie, A. Marcelli, A. Sheregii, E.M. Cestelli Guidi, M. Piccinini, M. Polit, J. Cebulski, J. Mycielsk, A. Ivanov-Omski, V.I. Sciesinska, E. Sciesinski, J. Burattini, E. |
| citation_txt | Statistical model analysis of local structure of quaternary
 sphalerite crystals / B.V. Robouch, A. Kisiel, A. Marcelli, E.M. Sheregii, M. Cestelli Guidi, M. Piccinini, J. Polit, J. Cebulski, A. Mycielski, V.I. Ivanov-Omskii, E. Sciesinska, J. Sciesinski, and E. Burattini // Физика низких температур. — 2007. — Т. 33, № 2-3. — С. 291-303. — Бібліогр.: 40 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | At the 2004 Ural International Winter School, we introduced the statistical strained tetrahedron
model and discussed ternary tetrahedron structured crystals. The model allows one to interpret
x-ray absorption fine structure (EXAFS) data and extract quantitative information on ion site occupation
preferences and on the size and shape of each elemental constituent of the configuration tetrahedra.
Here we extend the model to cover quaternary sphalerite crystal structures. We discuss the
two topologically different quaternary sphalerite systems: the pseudo balanced A₁₋xBxYyZ₁₋y (2:2
cation:anion ratio), and the unbalanced AxBx 
C₁₋x₋x 
Z or AXyYy 
Z₁₋y₋y (3:1 or 1:3 cation:anion ratios)
truly quaternary alloy systems. These structural differences cause preference values in pseudo
quaternaries to vary with the relative contents, but to remain constant in truly quaternary compounds.
We give equations to determine preference coefficient values from EXAFS or phonon spectra
and to extract nearest-neighbour inter-ion distances by EXAFS spectroscopy. The procedure is illustrated
and tested on CdMnSeTe, GaInAsSb, and ZnCdHgTe quaternary alloys.
|
| first_indexed | 2025-12-07T18:20:31Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-127732 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-12-07T18:20:31Z |
| publishDate | 2007 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Robouch, B.V. Kisie, A. Marcelli, A. Sheregii, E.M. Cestelli Guidi, M. Piccinini, M. Polit, J. Cebulski, J. Mycielsk, A. Ivanov-Omski, V.I. Sciesinska, E. Sciesinski, J. Burattini, E. 2017-12-27T11:01:11Z 2017-12-27T11:01:11Z 2007 Statistical model analysis of local structure of quaternary
 sphalerite crystals / B.V. Robouch, A. Kisiel, A. Marcelli, E.M. Sheregii, M. Cestelli Guidi, M. Piccinini, J. Polit, J. Cebulski, A. Mycielski, V.I. Ivanov-Omskii, E. Sciesinska, J. Sciesinski, and E. Burattini // Физика низких температур. — 2007. — Т. 33, № 2-3. — С. 291-303. — Бібліогр.: 40 назв. — англ. 0132-6414 PACS: 61.43. Dq https://nasplib.isofts.kiev.ua/handle/123456789/127732 At the 2004 Ural International Winter School, we introduced the statistical strained tetrahedron
 model and discussed ternary tetrahedron structured crystals. The model allows one to interpret
 x-ray absorption fine structure (EXAFS) data and extract quantitative information on ion site occupation
 preferences and on the size and shape of each elemental constituent of the configuration tetrahedra.
 Here we extend the model to cover quaternary sphalerite crystal structures. We discuss the
 two topologically different quaternary sphalerite systems: the pseudo balanced A₁₋xBxYyZ₁₋y (2:2
 cation:anion ratio), and the unbalanced AxBx 
 C₁₋x₋x 
 Z or AXyYy 
 Z₁₋y₋y (3:1 or 1:3 cation:anion ratios)
 truly quaternary alloy systems. These structural differences cause preference values in pseudo
 quaternaries to vary with the relative contents, but to remain constant in truly quaternary compounds.
 We give equations to determine preference coefficient values from EXAFS or phonon spectra
 and to extract nearest-neighbour inter-ion distances by EXAFS spectroscopy. The procedure is illustrated
 and tested on CdMnSeTe, GaInAsSb, and ZnCdHgTe quaternary alloys. Part of this work was supported by EU TARI-project
 contract HPRI-CT-1999-00088. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Структура и свойства полупроводников с переходными элементами Statistical model analysis of local structure of quaternary sphalerite crystals Article published earlier |
| spellingShingle | Statistical model analysis of local structure of quaternary sphalerite crystals Robouch, B.V. Kisie, A. Marcelli, A. Sheregii, E.M. Cestelli Guidi, M. Piccinini, M. Polit, J. Cebulski, J. Mycielsk, A. Ivanov-Omski, V.I. Sciesinska, E. Sciesinski, J. Burattini, E. Структура и свойства полупроводников с переходными элементами |
| title | Statistical model analysis of local structure of quaternary sphalerite crystals |
| title_full | Statistical model analysis of local structure of quaternary sphalerite crystals |
| title_fullStr | Statistical model analysis of local structure of quaternary sphalerite crystals |
| title_full_unstemmed | Statistical model analysis of local structure of quaternary sphalerite crystals |
| title_short | Statistical model analysis of local structure of quaternary sphalerite crystals |
| title_sort | statistical model analysis of local structure of quaternary sphalerite crystals |
| topic | Структура и свойства полупроводников с переходными элементами |
| topic_facet | Структура и свойства полупроводников с переходными элементами |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/127732 |
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