Infrared and EPR spectroscopic study of open-shell reactive intermediates: F + NH₃ in solid argon

• Datum: 2000
• Hauptverfasser: Misochko, Eugenii Ya., Goldschleger, Ilya U., Akimov, Alexander V., Wight, Charles A.
• Format: Artikel
• Sprache: English
• Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2000
• Schriftenreihe: Физика низких температур
• Schlagworte: Low-Temperature Physics and Chemistry in Cryomatrice
• Online Zugang: https://nasplib.isofts.kiev.ua/handle/123456789/129220
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Zitieren: Infrared and EPR spectroscopic study of open-shell reactive intermediates: F + NH₃ in solid argon / Eugenii Ya. Misochko, Ilya U. Goldschleger, Alexander V. Akimov, Charles A. Wight // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 981-991. — Бібліогр.: 43 назв. — англ.

Mobile F atoms react with NH₃ molecules in an argon matrix at temperatures T=7–35 K. The open-shell NH₂–HF complex was observed by EPR and infrared spectroscopies as the main product of this reaction. The hyperfine constants of the NH₂–HF complex aN=1.20 mT, aH=2.40 mT, and aF=0.70 mT were determine...