In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2

Aim. To establish anti-influenza activities for 8 compounds of adamantyl (alkyl, cycloalkyl) de-rivatives of aminopropanol-2 in vitro and in vivo investigations. Methods. The antiviral action of compounds was determined in vitro by reduction of infectious titer of the influenza virus in the Madin-Da...

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Published in:Вiopolymers and Cell
Date:2017
Main Authors: Voloshchuk, O.M., Korotkiy, Y.V., Rybalko, S.L., Starosila, D.B., Shirobokov, V.P.
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Language:English
Published: Інститут молекулярної біології і генетики НАН України 2017
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Cite this:In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 / O.M. Voloshchuk, Y.V. Korotkiy, S.L. Rybalko, D.B. Starosila, V.P. Shirobokov // Вiopolymers and Cell. — 2017. — Т. 33, № 6. — С. 453-462. — Бібліогр.: 21 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling Voloshchuk, O.M.
Korotkiy, Y.V.
Rybalko, S.L.
Starosila, D.B.
Shirobokov, V.P.
2019-06-13T14:17:13Z
2019-06-13T14:17:13Z
2017
In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 / O.M. Voloshchuk, Y.V. Korotkiy, S.L. Rybalko, D.B. Starosila, V.P. Shirobokov // Вiopolymers and Cell. — 2017. — Т. 33, № 6. — С. 453-462. — Бібліогр.: 21 назв. — англ.
0233-7657
DOI: http://dx.doi.org/10.7124/bc.000968
https://nasplib.isofts.kiev.ua/handle/123456789/153122
578.832.1:57.044:57.085.1/.2
Aim. To establish anti-influenza activities for 8 compounds of adamantyl (alkyl, cycloalkyl) de-rivatives of aminopropanol-2 in vitro and in vivo investigations. Methods. The antiviral action of compounds was determined in vitro by reduction of infectious titer of the influenza virus in the Madin-Darby Canine Kidney (MDCK) cell culture and in vivo on the model of influenza pneu-monia in mice. Results. Three of eight studied compounds inhibit the reproduction of the influ-enza virus strain A/FM/1/47(H1N1) by more than 2 lg ID50 in the concentration range from < 0.39 µg/ml (the compounds 30 and 33) to 1.56 µg/ml (the compound 5), their chemotherapeutic indices are 256 and 16, respectively. The experiments in vivo showed that in prophylactic scheme the efficiency index (EI) of the compounds 5 and 30 is 60 %; in therapeutic scheme EI of the compounds 5 and 33 is 100 % that is two times higher, than for rimantadine. Conclusions. High chemotherapeutic indices of the compounds 30, 33 and their ability to suppress the influenza virus reproduction in the MDCK cell culture by more than 2 lg ID50 indicate the anti-influenza activity of these compounds. It has been also confirmed by in vivo experiment.
Мета. Визначити антигрипозну активність у 8 сполук адамантан (алкіл, циклоалкіл) похідних амінопропанолу-2 в дослідах in vitro та in vivo. Методи. Оцінку противірусної дії сполук проводили in vitro за зниженням інфекційного титру вірусу грипу на культурі клітин, та in vivo на моделі грипозної пневмонії у мишей. Результати. В досліді in vitro 3 сполуки серед 8 досліджених пригнічують репродукцію вірусу грипу штаму А/FM/1/47(H1N1) на 2 lg ID50 і більше в концентраціях від < 0,39 мкг/мл (сполуки №№ 30 і 33) до 1,56 мкг/мл (сполука № 5), їх хіміотерапевтичні індекси стосовно цього вірусу становлять 256 та 16, відповідно. В досліді in vivo при профілактичній схемі досліду сполуки №№ 5 і 30 мають індекс ефективності (ІЕ) 60 %, а при лікувальній схемі досліду ІЕ сполук №№ 5 та 33 більше ніж в два рази перевищує цей показник у ремантадину і становить 100 %. Висновки. Високі хіміотерапев-тичні індекси та здатність пригнічувати репродукцію вірусу грипу на 2 lg ID50 і більше дозволяє віднести сполуки №№ 30, 33 і 5 до таких, що проявляють протигрипозну активність. Це також підтверджено в досліді in vivo.
Цель. Определить антигриппозную активность у 8 соединений адамантан (алкил, циклоалкил) производных аминопропанола-2 в экспериментах in vitro и in vivo. Методы. Противовирусное действие исследуемых соединений определяли in vitro по снижению инфекционного титра вируса гриппа в культуре клеток MDCK и in vivo на модели гриппозной пневмонии у мышей. Результаты. 3 соединения среди 8 исследованных подавляют репродукцию виру-са гриппа штамм А/FM/1/47(H1N1) на 2 lg ID50 и больше в концентрациях от < 0,39 мкг/мл (соединения №№ 30 и 33) до 1,56 мкг/мл (соединение № 5), их химиотерапевтические индексы (ХТИ) в отношении этого вируса состав-ляют 256 и 16, соответственно. В эксперименте in vivo при профилактической схеме опыта соединения №№ 5 и 30 имеют индекс эффективности (ИЭ) 60 %. ИЭ соединений №№ 5 и 33 при лечебной схеме опыта больше чем в два раза превышает этот показатель у Ремантадина и составляет 100 %. Выводы. Высокие ХТИ и способность подав-лять репродукцию вируса гриппа на 2 lg ID50 и более позволяют отнести соединения №№ 30, 33 и 5 к таким, что проявляют противогриппозную активность. Это также подтверждено в експриментах in vivo.
en
Інститут молекулярної біології і генетики НАН України
Вiopolymers and Cell
Viruses and Cell
In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2
Антигрипозна дія адамантан (алкіл, циклоалкіл) похідних амінопропанолу-2 в дослідах in vitro та in vivo
Антигриппозное действие адамантан (алкил, циклоалкил) производных аминопропанола-2 в экспериментах in vitro и in vivo
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2
spellingShingle In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2
Voloshchuk, O.M.
Korotkiy, Y.V.
Rybalko, S.L.
Starosila, D.B.
Shirobokov, V.P.
Viruses and Cell
title_short In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2
title_full In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2
title_fullStr In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2
title_full_unstemmed In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2
title_sort in vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2
author Voloshchuk, O.M.
Korotkiy, Y.V.
Rybalko, S.L.
Starosila, D.B.
Shirobokov, V.P.
author_facet Voloshchuk, O.M.
Korotkiy, Y.V.
Rybalko, S.L.
Starosila, D.B.
Shirobokov, V.P.
topic Viruses and Cell
topic_facet Viruses and Cell
publishDate 2017
language English
container_title Вiopolymers and Cell
publisher Інститут молекулярної біології і генетики НАН України
format Article
title_alt Антигрипозна дія адамантан (алкіл, циклоалкіл) похідних амінопропанолу-2 в дослідах in vitro та in vivo
Антигриппозное действие адамантан (алкил, циклоалкил) производных аминопропанола-2 в экспериментах in vitro и in vivo
description Aim. To establish anti-influenza activities for 8 compounds of adamantyl (alkyl, cycloalkyl) de-rivatives of aminopropanol-2 in vitro and in vivo investigations. Methods. The antiviral action of compounds was determined in vitro by reduction of infectious titer of the influenza virus in the Madin-Darby Canine Kidney (MDCK) cell culture and in vivo on the model of influenza pneu-monia in mice. Results. Three of eight studied compounds inhibit the reproduction of the influ-enza virus strain A/FM/1/47(H1N1) by more than 2 lg ID50 in the concentration range from < 0.39 µg/ml (the compounds 30 and 33) to 1.56 µg/ml (the compound 5), their chemotherapeutic indices are 256 and 16, respectively. The experiments in vivo showed that in prophylactic scheme the efficiency index (EI) of the compounds 5 and 30 is 60 %; in therapeutic scheme EI of the compounds 5 and 33 is 100 % that is two times higher, than for rimantadine. Conclusions. High chemotherapeutic indices of the compounds 30, 33 and their ability to suppress the influenza virus reproduction in the MDCK cell culture by more than 2 lg ID50 indicate the anti-influenza activity of these compounds. It has been also confirmed by in vivo experiment. Мета. Визначити антигрипозну активність у 8 сполук адамантан (алкіл, циклоалкіл) похідних амінопропанолу-2 в дослідах in vitro та in vivo. Методи. Оцінку противірусної дії сполук проводили in vitro за зниженням інфекційного титру вірусу грипу на культурі клітин, та in vivo на моделі грипозної пневмонії у мишей. Результати. В досліді in vitro 3 сполуки серед 8 досліджених пригнічують репродукцію вірусу грипу штаму А/FM/1/47(H1N1) на 2 lg ID50 і більше в концентраціях від < 0,39 мкг/мл (сполуки №№ 30 і 33) до 1,56 мкг/мл (сполука № 5), їх хіміотерапевтичні індекси стосовно цього вірусу становлять 256 та 16, відповідно. В досліді in vivo при профілактичній схемі досліду сполуки №№ 5 і 30 мають індекс ефективності (ІЕ) 60 %, а при лікувальній схемі досліду ІЕ сполук №№ 5 та 33 більше ніж в два рази перевищує цей показник у ремантадину і становить 100 %. Висновки. Високі хіміотерапев-тичні індекси та здатність пригнічувати репродукцію вірусу грипу на 2 lg ID50 і більше дозволяє віднести сполуки №№ 30, 33 і 5 до таких, що проявляють протигрипозну активність. Це також підтверджено в досліді in vivo. Цель. Определить антигриппозную активность у 8 соединений адамантан (алкил, циклоалкил) производных аминопропанола-2 в экспериментах in vitro и in vivo. Методы. Противовирусное действие исследуемых соединений определяли in vitro по снижению инфекционного титра вируса гриппа в культуре клеток MDCK и in vivo на модели гриппозной пневмонии у мышей. Результаты. 3 соединения среди 8 исследованных подавляют репродукцию виру-са гриппа штамм А/FM/1/47(H1N1) на 2 lg ID50 и больше в концентрациях от < 0,39 мкг/мл (соединения №№ 30 и 33) до 1,56 мкг/мл (соединение № 5), их химиотерапевтические индексы (ХТИ) в отношении этого вируса состав-ляют 256 и 16, соответственно. В эксперименте in vivo при профилактической схеме опыта соединения №№ 5 и 30 имеют индекс эффективности (ИЭ) 60 %. ИЭ соединений №№ 5 и 33 при лечебной схеме опыта больше чем в два раза превышает этот показатель у Ремантадина и составляет 100 %. Выводы. Высокие ХТИ и способность подав-лять репродукцию вируса гриппа на 2 lg ID50 и более позволяют отнести соединения №№ 30, 33 и 5 к таким, что проявляют противогриппозную активность. Это также подтверждено в експриментах in vivo.
issn 0233-7657
url https://nasplib.isofts.kiev.ua/handle/123456789/153122
citation_txt In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 / O.M. Voloshchuk, Y.V. Korotkiy, S.L. Rybalko, D.B. Starosila, V.P. Shirobokov // Вiopolymers and Cell. — 2017. — Т. 33, № 6. — С. 453-462. — Бібліогр.: 21 назв. — англ.
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fulltext 453 O. M. Voloshchuk, Y. V. Korotkiy, S. L. Rybalko © 2017 O. M. Voloshchuk et al.; Published by the Institute of Molecular Biology and Genetics, NAS of Ukraine on behalf of Biopolymers and Cell. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited UDC 578.832.1:57.044:57.085.1/.2 In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 O. M. Voloshchuk1, Y. V. Korotkiy2, S. L. Rybalko3, D. B. Starosila3, V. P. Shirobokov1 1 Bogomolets National Medical University 13, Shevchenko Blvd., Kyiv, Ukraine, 01601 2 Institute of organic chemistry NAS of Ukraine 5, Murmanska Str., Kyiv, Ukraine, 02660 3 Gromashevsky L. V. Institute of Epidemiology and Infection Diseases, NAMS of Ukraine 5, Amosova Str., Kyiv, Ukraine, 03038 post-ua@yandex.ua Aim. To establish anti-influenza activities for 8 compounds of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 in vitro and in vivo investigations. Methods. The antiviral ac- tion of compounds was determined in vitro by reduction of infectious titer of the influenza virus in the Madin-Darby Canine Kidney (MDCK) cell culture and in vivo on the model of influ- enza pneumonia in mice. Results. Three of eight studied compounds inhibit the reproduction of the influenza virus strain A/FM/1/47(H1N1) by more than 2 lg ID50 in the concentration range from < 0.39 µg/ml (the compounds 30 and 33) to 1.56 µg/ml (the compound 5), their chemotherapeutic indices are 256 and 16, respectively. The experiments in vivo showed that in prophylactic scheme the efficiency index (EI) of the compounds 5 and 30 is 60 %; in therapeu- tic scheme EI of the compounds 5 and 33 is 100 % that is two times higher, than for rimantadine. Conclusions. High chemotherapeutic indices of the compounds 30, 33 and their ability to sup- press the influenza virus reproduction in the MDCK cell culture by more than 2 lg ID50 indicate the anti-influenza activity of these compounds. It has been also confirmed by in vivo experiment. K e y w o r d s: influenza virus, adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2, antiviral activity. Introduction For today in the world and in Ukraine in par- ticular, is unstable epidemic situation for many infectious diseases, including viral. According to the WHO estimates by 2030, infection dis- eases will be one of the major causes of mortal- ity among people (Antimicrobial resistance: global report on surveillance 2014, http://apps. who.int/iris/bitstream/10665/112642/1/97892 41564748_eng.pdf?ua=1). Influenza is a lea der among the respiratory tract infections by the Viruses and Cell ISSN 1993-6842 (on-line); ISSN 0233-7657 (print) Biopolymers and Cell. 2017. Vol. 33. N 6. P 453–462 doi: http://dx.doi.org/10.7124/bc.000968 454 O. M. Voloshchuk, Y. V. Korotkiy, S. L. Rybalko et al. number of cases and distribution. Airborne droplets way of distribution of flu infection leads to the rapid spread of the pathogen, and high antigenic variability of the influenza virus results in the appearance of new strains causing epidemics and pandemics. According to the WHO data, the flu and flu-like illnesses affect annually 5 – 30 % of the world population. The flu and acute respiratory viral infections annu- ally affect about 15 million people in Ukraine [1]. Despite the recent achievements in diag- nostics and therapy, the problem of treatment of influenza remains a relevant problem, as well as the establishment of effective chemothera- peutic agents for prevention and therapy of this infection. Nowadays the process of creating new medicines commonly starts from finding new drug candidates – structural prototypes of future chemotherapeutic agents with the desired pharmacological effect [2]. The search for an- timicrobial compounds is carried out among new chemical classes as well as among new derivatives of already known compounds af- fecting certain targets. Since discovery of ada- mantane its derivatives have proven to be the most promising as viral inhibitors [3–6]. The best of them is aminoadamantane (amantadine, rimantadine) [3, 7], which entered the pharma- ceutical market and is successfully used as an anti-influenza drug. The adamantane molecule is highly reactive compared with other hydrocarbons, which al- lows obtaining a wide range of poly-function- al derivatives. The molecule can be modified by the C–H bond activation for the direct nu- cleophilic substitution or radical reactions [8–12]. It can be also modified by the introduc- tion of substituents or heterocyclic atoms for designing new derivatives [13, 14]. It is known from literature that amino alco- hols and the products of their substitution in the amino and hydroxyl groups have polyvalent pharmacological effects (stimulators or block- ers of α and β-adrenaline, adrenaline mimetics, antibiotics, etc.) [15, 16]. It is also known that adamantane containing amino alcohols dem- onstrates antiviral action [17]. The modification of β-adrena blockers structures via the introduc- tion of various adamantyl fragments as amino groups results in the appearance of antivirus effects [18]. Based on this knowledge it seemed advisable to study an antiviral effect of new adamantane derivatives containing amino al- cohols and their related alkyl and cycloalkyl structural analogs [19, 20]. Materials and Methods The synthesized compounds Investigated adamantanyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 were synthe- sized in Institute of Organic Chemistry of the NAS of Ukraine according to the procedures developed in [15]. The structure and purity of the synthesized compounds were proved via elemental analysis, proton magnetic resonance spectroscopy and chromatography mass spec- trometry methods. The common formula of the tested compounds is ROCH2CH(OH)CH2R1 where: R – Ad(CH2)2, R1 – cyclohexylamin (the compound 5); R – Ad(CH2)2, R1 – 1,1,3,3- tetramethylbutylamine (the compound 6); R – tretbutyl, R1 – 2,2,6,6-tetraethyl piperidin amine (the compound 33); R – allyl, R1 – 1,1,3,3-tetramethylbutyl-amine (the compound 40); R – tret-amyl, R1 – 2,2,6,6-tetramethyl- 4-hydroxy piperidine amine (the compound 455 In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 47); R – cyclopentyl, R1 – 2,2,6,6-tetramethyl- 4-hydroxy piperidine amine (the compound 48); R – bornyl, R1 – 2,2,6,6-tetramethyl-4-hy- droxy piperidine amine (the compound 51). The compounds 48 and 51 were investigated in the alkali form. Depending on the radicals structure all test- ed compounds were divided into the adaman- tane containing (compounds 5 and 6), bornyl containing (the compound 51), the compounds with cyclic substituents in alkoxy group (the compounds 30 and 48) and the compounds with alicyclic substituents in alkoxy group (the compounds 33, 40, 47). All synthesized com- pounds are colorless and odorless crystalline substances with different solubility in water and 96 % alcohol. The 1 mg/ml matrix solu- tions of the studied compounds were prepared using a medium for cell cultures without se- rum. These solutions were sterilized via filtra- tion through cellulose filter with 0.22 µm pore diameter. The solution was stored in sterile bottles at –20 °C before using. Virus and cell culture The mouse-adapted influenza virus A/ FM/1/47(H1N1) was cultivated in Madin- Darby Canine Kidney (MDCK) cells (ATCC, CCL-34). MDCK cells were cultured in Dulbecco’s modified Eagle’s medium (DMEM), supplemented with 5 % heat inac- tivated fetal bovine serum (FBS) in 37 °C incubator with 5 % CO2. The influenza A/ FM/1/47(H1N1) and MDCK cells were ob- tained from the Bank of cell cultures of the laboratory of experimental chemotherapy of viral infections of the L. V. Gromashevsky Institute of epidemiology and infectious dis- eases of NAMS of Ukraine. Virological tests in vitro Anti-influenza activity of the tested compounds was evaluated by chemotherapeutic index (CTI) determined as the ratio of the maximum tolerated dose (MTD) to the minimum active concentration (MAC). MTD was determined as the greatest con- centration of the tested compound that did not cause the cytopathic effect (CPE) in the mono- layer of MDCK cells [16, 17]. For this pur- pose, the growing MDCK cells were plated at a density of 1 × 105 cells/ml and incubated in 96-well plates for 24 h (37 °C, 5 % CO2). Then the cells were treated with the tested com- pounds of different concentration (3.12, 6.25, 12.5, 25, 50, 100 μg/ml) for 5 days. The wells containing no compounds were used as a neg- ative control. In the experiments, we used at least ten holes for each dilution of the sub- stance. The CPE was determined by changed cell morphology (degeneration or exfoliation of cells from the hole surface). MAC of the studied compounds was deter- mined by the degree of reduction of infectious titer of the virus according to the General es- tablished procedure [16, 17]. The virus titers were calculated as 50 % of tissue culture infec- tious dose (TCID50) using the Kerber formula (Manual for the virological investigation of polio, http://apps. who.int/iris/bitstream/10665/ 68762/1/WHO_IVB_04.10.pdf): Lg TCID50= L-d(S-0.5), where L – the initial dilution, d – the difference between Lg of serial dilutions, S – the sum of the proportions of tested objects, which gave a positive result. The hemagglutination inhibition test (HAI) was carried out to study the influence of tested compounds on the influenza virus hemagglu- http://apps 456 O. M. Voloshchuk, Y. V. Korotkiy, S. L. Rybalko et al. tination activity (HA). The tested substances diluted in the range of 50 – 0.36 mkg/ml were incubated with the virus (4 agglutination units) for 30 min at room temperature; 0.75 % eryth- rocytes suspension of Guinea pigs were added, shaken and left at room temperature for 60 min. As a titer of HAI was taken a limiting dilution, which gives a complete delay of the hemagglutination reaction, that is ++++. Virological studies in vivo The anti-influenza activity of tested compounds was studied via simulation of influenza pneu- monia in mice using prophylactic and therapeu- tic schemes of the compound introduction. In these studies, we used white outbred mice weighing 18–22 g, which were on the standard diet for at least 7 days. All experiments were performed with ten mice per group. For the prophylactic scheme the mice were intranasally (i.n.) inoculated with 0.2 ml of the tested compounds at 10×ID50 (50 %-mouse in- fectious dose; sub-lethal) 24 h before infection with the influenza virus. For the therapeutic scheme this procedure was carried out 24 h after infection of mice with the influenza virus. At the same time for both schemes, the control was a group of animals infected with the influenza virus without administration of the tested com- pounds. The influenza virus strain A/ FM/1/47(H1N1) with infectious titer in the MDCK cell culture 4.5 lg ID50, caused 100 % mortality of control group mice within 5 days. Observation of experimental animals was carried out for 7 days. It was also studied the effect of reference drugs in different regimens of admin- istration to mice with experimental influenza pneumonia. As the reference drugs we used the known flu drugs Tamiflu® of pharmaceutical company F. Hoffman-La Roche, Switzerland (75 mg per capsule) and Rimantadine of pharma- ceutical company “Darnitsa”, Ukraine (50 mg tablets), which were administered at a dose of 10 mg/kg of animal weight. The efficiency of protective action of the compounds was evaluated by the efficiency index (EI) of inhibition of lethality. EI of the tested substances was determined according to the formula [21]: EI = PC – 1 ×100 %, PC where PC — protection coefficient defined as the ratio of the number of animals at the begin- ning to that at the end of experiment. Results and Discussion The anti-influenza activity of new synthesized adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 was studied against the in- fluenza virus strain A/FM/1/47(H1N1). The antiviral activity of tested compounds 5, 6, 30, 33, 40, 47, 48, 51 was evaluated in vitro ex- periments by their chemotherapeutic index (CTI) determined as the ratio of the maximum tolerated dose (MTD) to the minimum active concentration (MAC). MTD of the tested com- pounds was determined by their cytotoxic ef- fect on a monolayer of the MDCK cells cul- ture. For this purpose, after 24-h cell growth the nutrient medium was replaced with the medium containing the tested compound in the concentration from 3.12 µg/ml to 100 µg/ml. In the control, no replacement was carried out. For the experiments at least ten wells with the cell culture were taken for each dilution of the compound. The level of CPE was determined 457 In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 by the change in cell morphology (degenera- tion or exfoliation of cells from the hole sur- face). MTD of the tested compound was taken as its highest concentration that did not cause degeneration of cells in all ten wells. The re- sults of MTD determination for the studied compounds are presented in figure 1. The MAC index of the tested substances was determined in vitro in a monolayer of the MDCK cells cultures by the level of reduction of infectious titer of the virus, in accordance with the General established procedure [16]. With this purpose the test-virus in a dose of 100 ID50 in 0.1 ml was introduced into the MDCK cells culture and incubated for 1 h at 37 °C. Next, the virus was removed by wash- ing with medium RPMI-1640, and the support medium (RPMI-1640 + 2% fetal serum) with the tested compounds in concentration from 0.39 mcg/ml to 50 µg/ml was added. A reduc- tion of infectious titer in the cell cultures trea- ted with different concentrations of the tested compounds not less than 2 lg ID50 in the ex- periment compared with control allowed us to establish MAC of the tested compounds for the influenza virus (see figure 2). According to the data in fig. 2 the com- pounds 47 and 48 have no influence on the reproduction of influenza virus in the studied concentrations (0.36 µg/ml to 50 µg/ml), they inhibit the development of virus-specific CPE in concentrations less than 2.0 lg ID50. The compounds 5, 6, 30, 33, 40, 51 inhibited the influenza virus reproduction more than 2.0 lg ID50 in concentrations from of 1.56 µg/ml (compound 5) to 6.25 µg/ml (the compound 40), which gives grounds to consider them to possess the antiviral activity. The compounds 30 and 33 were the most active against the influenza virus, their MAC was the smallest and amounted to < 0.39 µg/ml. Fig. 2. The MAC of test compounds for influenza virus. Fig. 1. The MTD of test compounds adamantyl (alkyl, cycloalkyl) of aminopropanol-2 derivatives 458 O. M. Voloshchuk, Y. V. Korotkiy, S. L. Rybalko et al. MTD of anti- influenza drugs Rimantadine and Tamiflu was determined by CPE on the monolayer of the MDCK cell culture, and the value of their MAC was established by the degree of reduction of infectious titer of the influenza virus (Table 1). The data in the tab- le 1 show that Rimantadine and Tamiflu were non-toxic to the MDCK cell cultures in a dose of 62.0 µg/ml and 250.0 µg/ml respectively, that corresponds to the value of MTD of these anti-influenza drugs. The value of ratio of MTD to MAC of the studied compounds, and that of anti-influenza drugs Tamiflu and Rimantadine allowed us to determine their CTI. These data are shown in table 2. Table 1. The value of CPE and MAC of anti-influenza drugs in relation to the influenza virus Concentration of drugs µg/ml anti-influenza drugs Rimantadine Tamiflu CPE Infectious titer of influenza virus (lg ID50) CPE Infectious titer of influenza virus (lg ID50) 500.0 0 NT 0 NT 250.0 0 NT 100 < 1.0 125.0 0 NT 100 < 1.0 62.0 100 4.0 100 < 1.0 31.0 100 4.0 100 < 1.0 15.5 100 4.0 100 < 1.0 7.75 100 4.0 100 4.0 Control of virus 100 4.0 100 4.0 * NT – not tested Table 2. MTD, МАC and CТІ of the tested compounds, anti-influenza drugs Tamiflu and Rimantadine compounds MTD, mcg/ml МАC, mcg/ml CТІ 5 25.0 1.56 16 6 12.5 3.125 4 30 > 50.0 0.36 256 33 > 50.0 0.36 256 40 > 50.0 6.25 8 47 12.5 0 – 48 < 100 0 – 51 12.5 3.125 4 Rimantadine 6200 0.36 172.2 Tamiflu 25 000 0.02 12 500 Table 3. The titer of HAI for compounds 5, 30, 33 Concentration of compounds μg/ml The titer of HAI* tested compounds 5 30 33 50.0 – – – 25.0 – ++++(1/512) – 12.5 – ++++(1/1024) – 6.25 – ++++(1/1024) – 3.1 – ++++(1/1024) – 1.55 – ++++(1/1024) – 0.72 ++++(1/512) ++++(1/1024) – 0.36 ++++(1/1024) ++++(1/1024) – Control of virus ++++(1/1024) ++++(1/1024) ++++(1/512) HAI * «-» – absence of hemagglutination ; «++++» – presence of hemagglutination,titer of HAI 459 In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 The values of MTD, МАC and CТІ of the compounds 30 and 33 correspond to the sub- stances highly active against the influenza virus. CTI of these compounds was equal to 256 and was higher than the same index of the anti-in- fluenza drug Rimantadine, CTI of which was 172.2. The compound 5 is active against the influenza virus, its CTI equal to 16. The value of CTI of the compounds 6, 40 and 51 was also more than 3 (4, 8 and 4 respectively) (Table 2). It is known that cells are sensitive to the influenza virus, bearing on their surface the receptors to viral glycoprotein of hemaggluti- nin (HA). The braking hemagglutination activ- ity of the viruses in some cases is associated with a loss of the virus infectivity; therefore, it is appropriate to evaluate the influence of compounds on the hemagglutinin properties of viruses. We examined the influence of the most active compounds 5, 30 and 33 on the hemagglutinate activity of the influenza virus using hemagglutination inhibition test (HAI) (Table 3). The titer of hemagglutination inhibition was the approved limiting dilution, which gives a complete delay of the hemagglutination reac- tion. The results of determination of the effect of various concentrations of the tested com- pounds on hemaglutinin properties of the in- fluenza virus are shown in table 3. The data in the table 3 show that the compounds 30 and 33 with the same value of MAC (< 0.39 µg/ ml) make different effects on the hemaglutina- tion properties of the influenza virus. The com- pound 33 influences the virus hemagglutinin in much smaller concentrations than the com- pound 30. The HAI titers for the compound № 33 is 0,36 µg/ml and the HAI titer for com- pound № 30 is only 50 µg/ml. The anti-influenza activity of the tested compounds 5, 30 and 33 was determined in the in vivo experiments on the model of mice Table 4. Anti-influenza action of the compounds 5, 30, 33 and the anti-influenza drugs in vivo experiment. Substances Concentration of substances mcg/ml The number of mice Protection coefficient Efficiency index (EI), %the total number of them died, (%) prophylactic scheme 5 1.55 10 4 (40 %) 2.5 60 30 0.36 10 4 (40 %) 2.5 60 33 0.36 10 8 (80 %) 1.25 20 Rimantadine 0.5 10 5 (50 %) 2 50 Tamiflu 0.02 10 2 (20 %) 5 80 therapeutic scheme 5 1.55 10 0 > 10 100 30 0.36 10 4 (40 %) 2.5 60 33 0.36 10 0 > 10 100 Rimantadine 0.5 10 6 (60 %) 1,66 39.7 Tamiflu 0.02 10 2 (20 %) 5 80 Control of virus 0 10 10 (100 %) – – 460 O. M. Voloshchuk, Y. V. Korotkiy, S. L. Rybalko et al. influenza pneumonia. The efficiency of the protective action of the tested compounds and anti-influenza drugs in the prophylactic and therapeutic schemes of their administration is shown in table 4. Among the studied substances only the compounds 5 and 30 protect mice from the lethal influenza infection in vivo experiments in the prophylactic scheme of administration (Table 6). Their efficiency indices are equal (60 %) and higher than the Remantadine EI by 10 %. Unlike the substances 5 and 30 the compound 33 did not provide a significant protective effect in the prophylactic scheme of administration. EI of the compound 33 was only 20 %, which is much less than that of Tamiflu (80 %). The compounds 5 and 33 showed a much greater protective effect in the therapeutic scheme of administration than in the prophylactic scheme of in vivo experiment. EI of these compounds was 100 % in the ther- apeutic scheme of administration, compared to the prophylactic scheme, where their EI values were 60 % and 20 % respectively. Comparison of the protective effects of newly synthesized compounds 5, 30, 33 and anti- influenza drugs Rimantadine and Tamiflu on the model of influenza pneumonia of mice in the prophylactic and therapeutic schemes of their administration is shown in figure 3. The EI values of tested compounds 5, 30, and 33 were significantly different for different schemes of the in vivo experiment (Fig. 3). The tested compounds were more effective in ther- apeutic scheme of their introduction, when influenza drugs showed the same effect in both variants of the experiment. Complete protec- tion against experimental influenza infection in mice was observed for compounds 5 and 33 in therapeutic scheme of their introduction. Their EI values were 100 %, that is more than twice higher than Rimantadine EI. The com- pound 30 showed identical efficiency in dif- ferent schemes of the in vivo experiment, its Fig. 3. Anti-influenza activity of the compounds 5, 30, 33 and anti-influen- za drugs Rimantadine and Tamiflu on the model of influenza pneumonia of mice in the prophylactic (1) and therapeutic (2) schemes of their adminis- tration. 461 In vitro and in vivo investigations on anti-influenza effect of adamantyl (alkyl, cycloalkyl) derivatives of aminopropanol-2 EI in both cases was 60 %. Noteworthy, for the compounds 30 and 33 an equally high CTI (256) was identified in vitro experiment, but these substances showed a different level of protective effect in vivo experiment. Conclusions Among eight tested adamantyl (alkyl, cycloal- kyl) derivatives of aminopropanol-2 in vitro and in vivo experiments anti-influenza activity was found for the compounds 5, 30 and 33. 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В досліді in vitro 3 сполуки серед 8 до- сліджених пригнічують репродукцію вірусу грипу штаму А/FM/1/47(H1N1) на 2 lg ID50 і більше в кон- центраціях від < 0,39 мкг/мл (сполуки №№ 30 і 33) до 1,56 мкг/мл (сполука № 5), їх хіміотерапевтичні індек- си стосовно цього вірусу становлять 256 та 16, відпо- відно. В досліді in vivo при профілактичній схемі до- сліду сполуки №№ 5 і 30 мають індекс ефективності (ІЕ) 60 %, а при лікувальній схемі досліду ІЕ сполук №№ 5 та 33 більше ніж в два рази перевищує цей по- казник у ремантадину і становить 100 %. Висновки. Високі хіміотерапевтичні індекси та здатність при- гнічувати репродукцію вірусу грипу на 2 lg ID50 і більше дозволяє віднести сполуки №№ 30, 33 і 5 до таких, що проявляють протигрипозну активність. Це також підтверджено в досліді in vivo. К л юч ов і с л ов а: вірус грипу, адамантил (алкіл, циклоалкіл) похідні амінопропанолу-2, антивірусна дія. Антигриппозное действие адамантил (алкил, циклоалкил) производных аминопропанола-2 в экспериментах in vitro и in vivo Е. М. Волощук, Ю. В. Короткий, С. Л. Рыбалко, Д. Б. Старосила, В. П. Широбоков Цель. Определить антигриппозную активность у 8 со- единений адамантил (алкил, циклоалкил) производных аминопропанола-2 в экспериментах in vitro и in vivo. Методы. Противовирусное действие исследуемых соединений определяли in vitro по снижению инфек- ционного титра вируса гриппа в культуре клеток MDCK и in vivo на модели гриппозной пневмонии у мышей. Результаты. 3 соединения среди 8 исследо- ванных подавляют репродукцию вируса гриппа штамм А/FM/1/47(H1N1) на 2 lg ID50 и больше в концентра- циях от < 0,39 мкг/мл (соединения №№ 30 и 33) до 1,56 мкг/мл (соединение № 5), их химиотерапевтиче- ские индексы (ХТИ) в отношении этого вируса состав- ляют 256 и 16, соответственно. В эксперименте in vivo при профилактической схеме опыта соединения №№ 5 и 30 имеют индекс эффективности (ИЭ) 60 %. ИЭ соединений №№ 5 и 33 при лечебной схеме опыта больше чем в два раза превышает этот показатель у Ремантадина и составляет 100 %. Выводы. Высокие ХТИ и способность подавлять репродукцию вируса гриппа на 2 lg ID50 и более позволяют отнести соеди- нения №№ 30, 33 и 5 к таким, что проявляют проти- вогриппозную активность. Это также подтверждено в експриментах in vivo. К л юч е в ы е с л ов а: вирус гриппа, адамантил (ал- кил, циклоалкил) производные аминопропанола-2, антивирусное действие. Received 05.01.2017