Accessing of the mixed-valence states in the zinc meso-ferrocenylporphyrin: experimental and theoretical data.

• Published in: Украинский химический журнал
• Date: 2005
• Main Authors: Nemykin, V.N., McGinn, M., Kqposov, A.Y., Tretyakova, I.N., Polshin, E.V., Loim, N.M., Abramova, N.V.
• Format: Article
• Language: English
• Published: Інститут загальної та неорганічної хімії ім. В.І. Вернадського НАН України 2005
• Subjects: Неорганическая и физическая химия
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/184072
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Accessing of the mixed-valence states in the zinc meso-ferrocenylporphyrin: experimental and theoretical data. / V.N. Nemykin, M. McGinn, A.Y. Kqposov, I.N. Tretyakova, E.V. Polshin, N.M. Loim, .N.V. Abramova // Украинский химический журнал. — 2005. — Т. 71, № 11-12. — С. 79-85. — Бібліогр.: 28 назв. — англ.

The formation of the stable at room temperature mixed-valence state in the zinc 5,10,15,20-tetra(ferrocenyl)porphyrin has been investigated by UV-V1S-NIR, Mossbauer, NMR, electrochemical, and theoretical (DFT) methods. On the basis of experimental and theoretical data it has been concluded that the...